Advertisements
Advertisements
Question
If a drop of liquid breaks into smaller droplets, it results in lowering of temperature of the droplets. Let a drop of radius R, break into N small droplets each of radius r. Estimate the drop in temperature.
Advertisements
Solution
When a big drop of radius R, breaks into N droplets each of radius r, the volume remains constant.
∴ Volume of big drop = N × Volume of each small drop
`4/3 πR^3 = N xx 4/3 πR^3`
or `R^3 = Nr^3`
or `N = R^3/r^3`
Now, the change in surface area = `4πR^2 - N4πr^2`
= `4π(R^2 - Nr^2)`
The energy released = T × ΔA
= `S xx 4π(R^2 - Nr^2)` .....[T = Surface tension]
Due to releasing of this energy. the temperature is lowered.
If ρ is the density and s is the specific heat of liquid and its temperature is lowered by Δθ then the energy released = msΔθ ......[s = specific heat Δθ = change in temperature]
`T xx 4π(R^2 - Nr^2) = (4/3 xx R^3 xx ρ)sΔθ` ......`[∴m = vρ = 4/3 πR^3ρ]`
⇒ Δθ = `(T xx 4π(R^2 - Nr^2))/(4/3 πR^3 ρ xx s)`
= `(3T)/(ρs) [R^2/R^3 - (Nr^2)/R^3]`
= `(3T)/(ρs) [1/R - ((R^3-r^3) xx r^2)/R^3]`
= `(3T)/(ρs) [1/R - 1/r]`
APPEARS IN
RELATED QUESTIONS
The surface tension of water at 0°C is 75.5 dyne/cm. Calculate surface tension of water at 25°C.
(α for water = 2.7×10-3/°C)
Fill in the blanks using the word(s) from the list appended with each statement
Surface tension of liquids generally . . . with temperatures (increases / decreases)
Mercury has an angle of contact equal to 140° with soda lime glass. A narrow tube of radius 1.00 mm made of this glass is dipped in a trough containing mercury. By what amount does the mercury dip down in the tube relative to the liquid surface outside? Surface tension of mercury at the temperature of the experiment is 0.465 N m–1. Density of mercury = 13.6 × 103 kg m–3
The total free surface energy of a liquid drop is `pisqrt2` times the surface tension of the liquid. Calculate the diameter of the drop in S.l. unit.
Calculate the work done in increasing the radius of a soap bubble in air from 1 cm to 2 cm. The surface tension of soap solution is 30 dyne/cm. (Π = 3.142).
It is said that a liquid rises or is depressed in capillary due to the surface tension. If a liquid neither rises nor depresses in a capillary, can we conclude that the surface tension of the liquid is zero?
Water near the bed of a deep river is quiet while that near the surface flows. Give reasons.
If water in one flask and castor oil in other are violently shaken and kept on a table, which will come to rest earlier?
The capillaries shown in figure have inner radii 0.5 mm, 1.0 mm and 1.5 mm respectively. The liquid in the beaker is water. Find the heights of water level in the capillaries. The surface tension of water is 7.5 × 10−2 N m−1.

Two large glass plates are placed vertically and parallel to each other inside a tank of water with separation between the plates equal to 1 mm. Find the rise of water in the space between the plates. Surface tension of water = 0.075 Nm−1.
A wire forming a loop is dipped into soap solution and taken out so that a film of soap solution is formed. A loop of 6.28 cm long thread is gently put on the film and the film is pricked with a needle inside the loop. The thread loop takes the shape of a circle. Find the tension the the thread. Surface tension of soap solution = 0.030 N m−1.
The energy stored in a soap bubble of diameter 6 cm and T = 0.04 N/m is nearly ______.
Describe an experiment to prove that friction depends on the nature of a surface.
What are the factors affecting the surface tension of a liquid?
Obtain an expression for the surface tension of a liquid by the capillary rise method.
Two spherical rain drops reach the surface of the earth with terminal velocities having ratio 16 : 9. The ratio of their surface area is ______.
Under isothermal conditions, two soap bubbles of radii 'r1' and 'r2' coalesce to form a big drop. The radius of the big drop is ______.
Surface tension is exhibited by liquids due to force of attraction between molecules of the liquid. The surface tension decreases with increase in temperature and vanishes at boiling point. Given that the latent heat of vaporisation for water Lv = 540 k cal kg–1, the mechanical equivalent of heat J = 4.2 J cal–1, density of water ρw = 103 kg l–1, Avagadro’s No NA = 6.0 × 1026 k mole–1 and the molecular weight of water MA = 18 kg for 1 k mole.
- Estimate the energy required for one molecule of water to evaporate.
- Show that the inter–molecular distance for water is `d = [M_A/N_A xx 1/ρ_w]^(1/3)` and find its value.
- 1 g of water in the vapor state at 1 atm occupies 1601 cm3. Estimate the intermolecular distance at boiling point, in the vapour state.
- During vaporisation a molecule overcomes a force F, assumed constant, to go from an inter-molecular distance d to d ′. Estimate the value of F.
- Calculate F/d, which is a measure of the surface tension.
A hot air balloon is a sphere of radius 8 m. The air inside is at a temperature of 60°C. How large a mass can the balloon lift when the outside temperature is 20°C? (Assume air is an ideal gas, R = 8.314 J mole–1K–1, 1 atm. = 1.013 × 105 Pa; the membrane tension is 5 Nm–1.)
A drop of water and a soap bubble have the same radii. Surface tension of soap solution is half of that of water. The ratio of excess pressure inside the drop and bubble is ______.
