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Match the species given in Column I with the properties mentioned in Column II. Column I Column II (i) BFX4− (a) Oxidation state of central atom is +4 (ii) AICI3 (b) Strong oxidising agent

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प्रश्न

Match the species given in Column I with the properties mentioned in Column II.

Column I Column II
(i) \[\ce{BF^{-}4}\] (a) Oxidation state of central atom is +4
(ii) AICI3 (b) Strong oxidising agent
(iii) SnO (c) Lewis acid
(iv) PbO2 (d) Can be further oxidised
  (e) Tetrahedral shape
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उत्तर

Column I Column II
(i) \[\ce{BF^{-}4}\] (e) Tetrahedral shape
(ii) AICI3 (c) Lewis acid
(iii) SnO (d) Can be further oxidised
(iv) PbO2 (b) Strong oxidising agent

Explanation:

(i) \[\ce{BF^{-}4}\]: Tetrahedral shape, sp3 hybridisation, regular geometry.

(ii) AlCl3: Octet of Al not complete, acts as Lewis acid.

(iii) SnO: Sn2+ can show +4 oxidation state.

(iv) PbO2: Due to inert pair effect, Pb4+ is less stable than Pb2+ and hence acts as strong oxidising agent.

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अध्याय 11: The p-block Elements - Multiple Choice Questions (Type - I) [पृष्ठ १३९]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 11
अध्याय 11 The p-block Elements
Multiple Choice Questions (Type - I) | Q 36 | पृष्ठ १३९

संबंधित प्रश्न

What happens when BF3 is reacted with ammonia?


What do you understand by inert pair effect?


Write a balanced equation for Al + NaOH → ?


The geometry of a complex species can be understood from the knowledge of type of hybridisation of orbitals of central atom. The hybridisation of orbitals of central atom in [Be(OH)4]– and the geometry of the complex are respectively.


Ionisation enthalpy (∆iH1kJ mol–1) for the elements of Group 13 follows the order.


In the structure of diborane ______.


The most commonly used reducing agent is ______.


Cement, the important building material is a mixture of oxides of several elements. Besides calcium, iron and sulphur, oxides of elements of which of the group (s) are present in the mixture?


Which of the following statements are correct. Answer on the basis of Figure.

(i) The two birdged hydrogen atoms and the two boron atoms lie in one plane;

(ii) Out of six B – H bonds two bonds can be described in terms of 3 centre 2-electron bonds.

(iii) Out of six B – H bonds four B – H bonds can be described in terms of 3 centre 2 electron bonds;

(iv) The four-terminal B – H bonds are two centre-two electron regular bonds.


Explain why the following compounds behave as Lewis acids?

BCl3


When BCl3 is treated with water, it hydrolyses and forms [B[OH]4]– only whereas AlCl3 in acidified aqueous solution forms [Al(H2O)6]3+ ion. Explain what is the hybridisation of boron and aluminium in these species?


Explain the following:

PbX2 is more stable than PbX4.


Explain the following:

Electron gain enthalpy of chlorine is more negative as compared to fluorine.


Explain the following:

Tl (NO3)3 acts as an oxidising agent.


Match the species given in Column I with the hybridisation given in Column II.

Column I Column II
(i) Boron in [B(OH)4]– (a) sp2
(ii) Aluminium in [Al(H2O)6]3+ (b) sp3
(iii) Boron in B2H6 (c) sp3d2
(iv) Carbon in Buckminsterfullerene  
(v) Silicon in \[\ce{SiO^{4-}4}\]  
(vi) Germanium in [GeCl6]2–  

Describe the general trends in the following properties of the elements in Groups 13 and 14.

Atomic size


Account for the following observations:

Though fluorine is more electronegative than chlorine yet BF3 is a weaker Lewis acid than BCl3 


Three pairs of compounds are given below. Identify that compound in each of the pairs which has group 13 element in more stable oxidation state. Give reason for your choice. State the nature of bonding also.

TlCl3, TlCl


Three pairs of compounds are given below. Identify that compound in each of the pairs which has group 13 element in more stable oxidation state. Give reason for your choice. State the nature of bonding also.

AlCl3 , AlCl


Which one of the following is the correct statement?


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