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प्रश्न
Complete the following chemical equations:
\[\ce{Z + 3 LiAlH4 -> X + 3LiF + 3AlF_3}\]
\[\ce{X + 6H2 -> Y + 6H2}\]
\[\ce{3X + 3O2 ->[Δ] B2O3 + 3H2O}\]
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उत्तर
\[\ce{\underset{(Z)}{4BF3} + 3LiAlH4 -> \underset{(X)}{2B2H6} + 3LiF + 3AlF3}\]
\[\ce{\underset{(X)}{B2H6} + 6H2O -> \underset{(Y)}{2H3BO3} + 6H2}\]
\[\ce{\underset{(X)}{B2H6} + 3O2 ->[Δ] B2O3 + 3H2O}\]
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संबंधित प्रश्न
If B–Cl bond has a dipole moment, explain why BCl3 molecule has zero dipole moment.
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In the structure of diborane ______.
Dry ice is ______.
Which of the following statements are correct. Answer on the basis of Figure.

(i) The two birdged hydrogen atoms and the two boron atoms lie in one plane;
(ii) Out of six B – H bonds two bonds can be described in terms of 3 centre 2-electron bonds.
(iii) Out of six B – H bonds four B – H bonds can be described in terms of 3 centre 2 electron bonds;
(iv) The four-terminal B – H bonds are two centre-two electron regular bonds.
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Explain the following:
PbX2 is more stable than PbX4.
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Electron gain enthalpy of chlorine is more negative as compared to fluorine.
Identify the compounds A, X and Z in the following reactions:
\[\ce{X ->[Δ][370 K] HBO2 ->[Δ][> 370 K] Z}\]
Match the species given in Column I with the hybridisation given in Column II.
| Column I | Column II |
| (i) Boron in [B(OH)4]– | (a) sp2 |
| (ii) Aluminium in [Al(H2O)6]3+ | (b) sp3 |
| (iii) Boron in B2H6 | (c) sp3d2 |
| (iv) Carbon in Buckminsterfullerene | |
| (v) Silicon in \[\ce{SiO^{4-}4}\] | |
| (vi) Germanium in [GeCl6]2– |
Describe the general trends in the following properties of the elements in Groups 13 and 14.
Atomic size
Describe the general trends in the following properties of the elements in Groups 13 and 14.
Ionisation enthalpy
Describe the general trends in the following properties of the elements in Groups 13 and 14.
Oxidation states
Describe the general trends in the following properties of the elements in Groups 13 and 14.
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TlCl3, TlCl
Three pairs of compounds are given below. Identify that compound in each of the pairs which has group 13 element in more stable oxidation state. Give reason for your choice. State the nature of bonding also.
AlCl3 , AlCl
