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प्रश्न
Account for the following observations:
The +1 oxidation state of thallium is more stable than its +3 state.
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उत्तर
As we move down the group in group 13 the participation of s-electrons in bond formation decreases the primary reason behind this is the inert pair effect. In this the p-electrons take part in bond formation and more energy is required to unpair the valence electrons to make them participate in bonding. Due to this the lower oxidation state of elements becomes stable than the higher oxidation state. As for thallium, +1 oxidation state is more stable than +3.
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संबंधित प्रश्न
What do you understand by inert pair effect?
Write a balanced equation for Al + NaOH → ?
Which of the following oxides is acidic in nature?
Ionisation enthalpy (∆iH1kJ mol–1) for the elements of Group 13 follows the order.
In the structure of diborane ______.
Which of the following statements are correct. Answer on the basis of Figure.
(i) The two birdged hydrogen atoms and the two boron atoms lie in one plane;
(ii) Out of six B – H bonds two bonds can be described in terms of 3 centre 2-electron bonds.
(iii) Out of six B – H bonds four B – H bonds can be described in terms of 3 centre 2 electron bonds;
(iv) The four-terminal B – H bonds are two centre-two electron regular bonds.
Aluminium dissolves in mineral acids and aqueous alkalies and thus shows amphoteric character. A piece of aluminium foil is treated with dilute hydrochloric acid or dilute sodium hydroxide solution in a test tube and on bringing a burning matchstick near the mouth of the test tube, a pop sound indicates the evolution of hydrogen gas. The same activity when performed with concentrated nitric acid, reaction doesn’t proceed. Explain the reason.
Explain the following:
Tl (NO3)3 acts as an oxidising agent.
Describe the general trends in the following properties of the elements in Groups 13 and 14.
Atomic size
Describe the general trends in the following properties of the elements in Groups 13 and 14.
Ionisation enthalpy
Account for the following observations:
Though fluorine is more electronegative than chlorine yet BF3 is a weaker Lewis acid than BCl3
Three pairs of compounds are given below. Identify that compound in each of the pairs which has group 13 element in more stable oxidation state. Give reason for your choice. State the nature of bonding also.
TlCl3, TlCl
Three pairs of compounds are given below. Identify that compound in each of the pairs which has group 13 element in more stable oxidation state. Give reason for your choice. State the nature of bonding also.
InCl3, InCl
A nonmetallic element of group 13, used in making bullet proof vests is extremely hard solid of black colour. It can exist in many allotropic forms and has unusually high melting point. Its trifluoride acts as Lewis acid towards ammonia. The element exihibits maximum covalency of four. Identify the element and write the reaction of its trifluoride with ammonia. Explain why does the trifluoride act as a Lewis acid.
Boron compounds behave as Lewis acids because of their ______.
A group 13 element ‘X’ reacts with chlorine gas to produce a compound XCl3. XCl3 is electron deficient and easily reacts with NH3 to form \[\ce{Cl3X –> NH3}\] adduct; however, XCl3 does not dimerize X is ______.
Which one of the following is the correct statement?
Taking stability as the factor, which one of the following represents the correct relationship?
