हिंदी
कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान कक्षा ११

If B–Cl bond has a dipole moment, explain why BCl3 molecule has zero dipole moment.

Advertisements
Advertisements

प्रश्न

If B–Cl bond has a dipole moment, explain why BCl3 molecule has zero dipole moment.

संक्षेप में उत्तर
एक पंक्ति में उत्तर
Advertisements

उत्तर १

As a result of the difference in the electronegativities of B and Cl, the B–Cl bond is polar in nature. However, the BCl3 molecule is non-polar. This is because BCl3 is trigonal planar in shape. It is a symmetrical molecule. Hence, the respective dipole-moments of the B–Cl bond cancel each other, thereby causing a zero-dipole moment.

shaalaa.com

उत्तर २

B-Cl bond has dipole moment because of polarity. In BCl3 since the molecule is symmetrical (planar). Thus the polarities cancel out.

shaalaa.com
  क्या इस प्रश्न या उत्तर में कोई त्रुटि है?

संबंधित प्रश्न

How can you explain higher stability of BClas compared to TlCl3?


What happens when BF3 is reacted with ammonia?


Write a balanced equation for Al + NaOH → ?


Write a balanced equation for B2H6 + NH3 → ?


The geometry of a complex species can be understood from the knowledge of type of hybridisation of orbitals of central atom. The hybridisation of orbitals of central atom in [Be(OH)4] and the geometry of the complex are respectively.


Which of the following oxides is acidic in nature?


The most commonly used reducing agent is ______.


Cement, the important building material is a mixture of oxides of several elements. Besides calcium, iron and sulphur, oxides of elements of which of the group (s) are present in the mixture?


Which of the following statements are correct. Answer on the basis of Figure.

(i) The two birdged hydrogen atoms and the two boron atoms lie in one plane;

(ii) Out of six B – H bonds two bonds can be described in terms of 3 centre 2-electron bonds.

(iii) Out of six B – H bonds four B – H bonds can be described in terms of 3 centre 2 electron bonds;

(iv) The four-terminal B – H bonds are two centre-two electron regular bonds.


When BCl3 is treated with water, it hydrolyses and forms [B[OH]4] only whereas AlCl3 in acidified aqueous solution forms [Al(H2O)6]3+ ion. Explain what is the hybridisation of boron and aluminium in these species?


Aluminium dissolves in mineral acids and aqueous alkalies and thus shows amphoteric character. A piece of aluminium foil is treated with dilute hydrochloric acid or dilute sodium hydroxide solution in a test tube and on bringing a burning matchstick near the mouth of the test tube, a pop sound indicates the evolution of hydrogen gas. The same activity when performed with concentrated nitric acid, reaction doesn’t proceed. Explain the reason.


Explain the following:

Tl (NO3)3 acts as an oxidising agent.


Identify the compounds A, X and Z in the following reactions:

\[\ce{X ->[Δ][370 K] HBO2 ->[Δ][> 370 K] Z}\]


Account for the following observations:

Though fluorine is more electronegative than chlorine yet BF3 is a weaker Lewis acid than BCl3 


Account for the following observations:

The +1 oxidation state of thallium is more stable than its +3 state.


Three pairs of compounds are given below. Identify that compound in each of the pairs which has group 13 element in more stable oxidation state. Give reason for your choice. State the nature of bonding also.

TlCl3, TlCl


Three pairs of compounds are given below. Identify that compound in each of the pairs which has group 13 element in more stable oxidation state. Give reason for your choice. State the nature of bonding also.

AlCl3 , AlCl


Three pairs of compounds are given below. Identify that compound in each of the pairs which has group 13 element in more stable oxidation state. Give reason for your choice. State the nature of bonding also.

InCl3, InCl


Taking stability as the factor, which one of the following represents the correct relationship?


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×