Advertisements
Advertisements
प्रश्न
How the following conversion can be carried out?
Ethyl chloride to propanoic acid.
Write the chemical equation to convert the following:
Ethyl chloride to propanoic acid.
Advertisements
उत्तर
\[\ce{\underset{Ethyl chloride}{CH3CH2Cl} ->[KCN/EtOH-H2O][nucleophilic substitution] \underset{Propanenitrile}{CH3CH2CN} ->[H+/H2O][hydrolysis] \underset{Propanoic acid}{CH3CH2COOH}}\]
संबंधित प्रश्न
Write the structure of the major organic product in the following reaction:
\[\ce{CH3CH(Br)CH2CH3 + NaOH ->[water]}\]
Arrange the compounds of the following set in order of reactivity towards SN2 displacement:
1-Bromo-3-methylbutane, 2-Bromo-2-methylbutane, 2-Bromo-3-methylbutane
The treatment of alkyl chlorides with aqueous KOH leads to the formation of alcohols but in the presence of alcoholic KOH, alkenes are major products. Explain.
Answer the following question.
Write one stereochemical difference between SN1 and SN2 reactions.
Which of the following is optically inactive?
Which of the following is an optically active compound?
Racemic compound has ____________.
The increasing order of reactivity towards SN1 mechanism is:
(I) \[\begin{array}{cc}
\ce{CH3-CH-CH2-CH3}\\
|\phantom{........}\\
\ce{CH3}\phantom{.....}
\end{array}\]
(II) CH3CH2CH2Cl
(III) P–CH3O–C6H4–CH2Cl
Which of the following alkyl halides will undergo SN1 reaction most readily?
Which of the compounds will react faster in SN1 reaction with the –OH ion?
\[\ce{CH3-CH2-Cl}\] or \[\ce{C6H5-CH2-Cl}\]
Compound ‘A’ with molecular formula \[\ce{C4H9Br}\] is treated with aq. \[\ce{KOH}\] solution. The rate of this reaction depends upon the concentration of the compound ‘A’ only. When another optically active isomer ‘B’ of this compound was treated with aq. \[\ce{KOH}\] solution, the rate of reaction was found to be dependent on concentration of compound and \[\ce{KOH}\] both.
(i) Write down the structural formula of both compounds ‘A’ and ‘B’.
(ii) Out of these two compounds, which one will be converted to the product with inverted configuration.
How do polar solvents help in the first step in SN1 mechanism?
Cyanide ion acts as an ambident nucleophile. From which end it acts as a stronger nucleophile in aqueous medium? Give reason for your answer.
Racemisation occurs in ______.
An organic compound A with the molecular formula (+) C4H9Br undergoes hydrolysis to form (+) C4H9OH. Give the structure of A and write the mechanism of the reaction.
Acetic anhydride from acetic acid
Which alkyl halide from the following pair would you expect to react more rapidly by an SN2 mechanism? Explain your answer.
\[\begin{array}{cc}\ce{CH3CH2CHCH3}\\
\phantom{.....}|\\
\phantom{......}\ce{Br}\\
\end{array}\] or \[\begin{array}{cc}\phantom{.......}\ce{CH3}\\
\phantom{...}|\\
\ce{H3C - C - Br}\\
\phantom{...}|\\
\phantom{.......}\ce{CH3}\\
\end{array}\]
The compound that will undergo SN1 reaction with the fastest rate is:
