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प्रश्न
Retention of configuration is observed in ______.
विकल्प
SN1 reaction
SN2 reaction
Neither SN1 nor SN2 reaction
SN2 reaction as well as SN1 reaction
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उत्तर
Retention of configuration is observed in SN1 reaction.
Explanation:
Both retention and inverted products are generated in SN1 reactions, but only the inverted product is formed in SN2 reactions.
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संबंधित प्रश्न
Discuss the mechanism of alkaline hydrolysis of bromomethane.
Which compound in the following pair reacts faster in SN2 reaction with OH–?
- CH3Br or CH3
- CH3Cl, (CH3)3CCl
The process of separation of a racemic modification into d and l-enantiomers is called ____________.
Identify X and Y in the following sequence:
\[\ce{C2H5Br ->[X] Product ->[Y] C3H7NH2}\]
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Ethylene chloride and ethylidene chloride are isomers. Identify the correct statements.
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(ii) Both the compounds form same product on treatment with aq.NaOH.
(iii) Both the compounds form same product on reduction.
(iv) Both the compounds are optically active.
Chlorination of alkanes is an example of
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| I | II | III | IV |
Which of the following compounds will show retention in configuration on nucleophile substitution by OH− ion?
The following questions are case-based questions. Read the passage carefully and answer the questions that follow:
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Nucleophilic Substitution: Influences of solvent polarity: The reaction rate (SN2) of 2-bromopropane and NaOH in ethanol containing 40% water is twice slower than in absolute ethanol. Hence the level of solvent polarity has an influence on both SN1 and SN2 reactions but with different results. Generally speaking, a weak polar solvent is favourable for SN2 reaction, while a strong polar solvent is favourable for SN1. Generally speaking, the substitution reaction of tertiary haloalkane is based on SN1 mechanism in solvents with a strong polarity (for example ethanol containing water). |
Answer the following questions:
(a) Why racemisation occurs in SN1? (1)
(b) Why is ethanol less polar than water? (1)
(c) Which one of, the following in each pair is more reactive towards SN2 reaction? (2)
(i) CH3 – CH2 – I or CH3CH2 – Cl
(ii)

OR
(c) Arrange the following in the increasing order of their reactivity towards SN1 reactions: (2)
(i) 2-Bromo-2-methylbutane, 1-Bromo-pentane, 2-Bromo-pentane
(ii) 1-Bromo-3-methylbutane, 2-Bromo-2-methylbutane, 2-Bromo-3- methylbutane




