Advertisements
Advertisements
प्रश्न
The stability order for carbocation is _______.
(A) 2° > 3° > 1°
(B) 3° > 2° > 1°
(C) 3° > 1° > 2°
(D) 1° > 3° > 2°
Advertisements
उत्तर
(B) 3° > 2° > 1°
APPEARS IN
संबंधित प्रश्न
Which would undergo SN1 reaction faster in the following pair and why?

Given reasons: C–Cl bond length in chlorobenzene is shorter than C–Cl bond length in CH3–Cl.
In the following pair of halogen compounds, which compound undergoes a faster SN1 reaction?

Write the isomers of the compound having the formula C4H9Br.
Write the structure of the major organic product in the following reaction:
\[\ce{CH3CH2Br + KCN ->[aq{.} ethanol]}\]
Arrange the compounds of the following set in order of reactivity towards SN2 displacement:
1-Bromo-3-methylbutane, 2-Bromo-2-methylbutane, 2-Bromo-3-methylbutane
Which would undergo SN2 reaction faster in the following pair and why ?
CH3 – CH2 – Br and CH3 – CH2 – I
Answer the following question.
Write one stereochemical difference between SN1 and SN2 reactions.
Which one of the following halogen compounds is difficult to be hydrolysed by SN1 mechanism?
Tertiary alkyl halides are practically inert to substitution by SN2 mechanism because of ____________.
Which of the following is an optically active compound?
An important chemical method to resolve a racemic mixture makes use of the formation of ______.
Which of the following compounds is optically active?
Which of the following compounds will give a racemic mixture on nucleophilic substitution by OH ion?
1-Bromoethane, 1-Bromopropane, 1-Bromobutane, Bromobenzene
Complete the following analogy:
Same molecular formula but different structures: A : : Non superimposable mirror images: B
Which of the compounds will react faster in SN1 reaction with the –OH ion?
\[\ce{CH3-CH2-Cl}\] or \[\ce{C6H5-CH2-Cl}\]
Elimination reactions (especially β-elimination) are as common as the nucleophilic substitution reaction in case of alkyl halides. Specify the reagents used in both cases.
Cyanide ion acts as an ambident nucleophile. From which end it acts as a stronger nucleophile in aqueous medium? Give reason for your answer.
Why are aryl halides less reactive towards nucleophilic substitution reactions than alkyl halides?
In which reaction mechanism carbocation is formed?
The major product formed in the following reaction is:

Retention of configuration is observed in ______.
Convert bromoethane to propanamine.
Identify the product in the following reaction: 
Explain why Grignard reagents should be prepared under anhydrous conditions.
Which alkyl halide from the following pair would you expect to react more rapidly by an SN2 mechanism? Explain your answer.
\[\begin{array}{cc}\ce{CH3CH2CHCH3}\\
\phantom{.....}|\\
\phantom{......}\ce{Br}\\
\end{array}\] or \[\begin{array}{cc}\phantom{.......}\ce{CH3}\\
\phantom{...}|\\
\ce{H3C - C - Br}\\
\phantom{...}|\\
\phantom{.......}\ce{CH3}\\
\end{array}\]
Consider the reactions,
(i) \[\begin{array}{cc}
\phantom{}\ce{\underset{}{(CH3)2CH - CH2Br} ->[C2H5OH] \underset{}{(CH3)2CH - CH2OC2H5 + HBr}}\\
\end{array}\]
(ii) \[\begin{array}{cc}
\phantom{}\ce{\underset{}{(CH3)2CH - CH2Br} ->[C2H5O-] \underset{}{(CH3)2CH - CH2OC2H5 + Br-}}\\
\end{array}\]
The mechanisms of reactions (i) and (ii) are respectively:
