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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

How the following conversion can be carried out? Ethyl chloride to propanoic acid - Chemistry

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प्रश्न

How the following conversion can be carried out?

Ethyl chloride to propanoic acid.

Write the chemical equation to convert the following:

Ethyl chloride to propanoic acid.

रासायनिक समीकरणे/रचना
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उत्तर

\[\ce{\underset{Ethyl chloride}{CH3CH2Cl} ->[KCN/EtOH-H2O][nucleophilic substitution] \underset{Propanenitrile}{CH3CH2CN} ->[H^+/H2O][hydrolysis] \underset{Propanoic acid}{CH3CH2COOH}}\]

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पाठ 6: Haloalkanes and Haloarenes - Exercises [पृष्ठ १९१]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
पाठ 6 Haloalkanes and Haloarenes
Exercises | Q 6.19 (xi) | पृष्ठ १९१

संबंधित प्रश्‍न

Out of , which is more reactive towards SN1 reaction and why?


Write the structure of the major product in each of the following reaction :


Which alkyl halide from the following pair would you expect to react more rapidly by an SN2 mechanism? Explain your answer.

CH3CH2CH2CH2Br or \[\begin{array}{cc}
\ce{CH3CH2CHCH3}\\
\phantom{...}|\\
\phantom{....}\ce{Br}\ 
\end{array}\]


In the following pair of halogen compounds, which compound undergoes a faster SN1 reaction?


Write the isomers of the compound having the formula C4H9Br.


Write the mechanism of the following reaction:

\[\ce{{n}BuBr + KCN ->[EtOH-H2O] {n}BuCN}\]


What is the action of the following on ethyl bromide?

moist silver oxide


Which one is most reactive towards SN1 reaction?


Tertiary alkyl halides are practically inert to substitution by SN2 mechanism because of ____________.


The increasing order of nucleophilicity would be:


Which of the following compound will undergo racemisation when reacts with aq. KOH?

(i)

(ii)

CH3CH2CH2Cl

(iii)

\[\begin{array}{cc}
\ce{CH3}\phantom{..}\\
|\phantom{....}\\
\ce{CH3-CH-CH2Cl}
\end{array}\]

(iv)

\[\begin{array}{cc}
\phantom{..}\ce{H}\\
\phantom{..}|\\
\ce{CH3-C-Cl}\\
\phantom{..}|\\
\phantom{.....}\ce{C2H5}
\end{array}\]


A primary alkyl halide would prefer to undergo ______.


Which of the following statements are correct about this reaction?

(i) The given reaction follows SN2 mechanism.

(ii) (b) and (d) have opposite configuration.

(iii) (b) and (d) have same configuration.

(iv) The given reaction follows SN1 mechanism.


Compound ‘A’ with molecular formula \[\ce{C4H9Br}\] is treated with aq. \[\ce{KOH}\] solution. The rate of this reaction depends upon the concentration of the compound ‘A’ only. When another optically active isomer ‘B’ of this compound was treated with aq. \[\ce{KOH}\] solution, the rate of reaction was found to be dependent on concentration of compound and \[\ce{KOH}\] both.

(i) Write down the structural formula of both compounds ‘A’ and ‘B’.

(ii) Out of these two compounds, which one will be converted to the product with inverted configuration.


How do polar solvents help in the first step in SN1 mechanism?


Aryl halides are extremely less reactive towards nucleophilic substitution. Predict and explain the order of reactivity of the following compounds towards nucleophilic substitution:

(I)
(II)
(III)

The major product formed in the following reaction is:


Among the following compounds I - IV, which one forms a yellow precipitate on reacting sequentially with (i) NaOH (ii) dil. HNO3 (iii) AgNO3?

I II III IV

Inversion of configuration occurs in ______.


An organic compound A with the molecular formula (+) C4H9Br undergoes hydrolysis to form (+) C4H9OH. Give the structure of A and write the mechanism of the reaction.


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