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प्रश्न
Out of C6H5CH2Cl and C6H5CHClC6H5, which is more easily hydrolysed by aqueous KOH.
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उत्तर
C6H5CHClC6H5 is hydrolysed faster.
- The hydrolysis of an alkyl halide is a nucleophilic substitution reaction. For aryl halides, this occurs through the SN1 method, resulting in a carbocation.
- C6H5CH2Cl or benzyl chloride gives
a carbocation, while C6H5CHClC6H5 generates 
. - Out of I and II, carbocation II is more stable. Two attached phenyl rings on the carbon carry the positive charge.
- This leads to increased delocalisation of the positive charge and greater carbocation stability. This leads to faster formation of (II) and easier hydrolysis of the resulting halide than benzyl chloride.
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संबंधित प्रश्न
Write the structure of an isomer of compound C4H9Br which is most reactive towards SN1 reaction
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How do you convert the following:
Ethanol to propanenitrile
How will you bring about the following conversion?
Toluene to benzyl alcohol
Write the mechanism of the following reaction:
\[\ce{{n}BuBr + KCN ->[EtOH-H2O] {n}BuCN}\]
SN1 reactions are accompanied by racemization in optically active alkyl halides.
Given reasons: SN1 reactions are accompanied by racemization in optically active alkyl halides.
Optically active isomers but not mirror images are called ____________.
Which among MeX, RCH2X, R2CHX and R3CX is most reactive towards SN2 reaction?
Complete the following analogy:
Same molecular formula but different structures: A : : Non superimposable mirror images: B
Which of the following statements are correct about the kinetics of this reaction?
(i) The rate of reaction depends on the concentration of only (b).
(ii) The rate of reaction depends on concentration of both (a) and (b).
(iii) Molecularity of reaction is one.
(iv) Molecularity of reaction is two.
Ethylene chloride and ethylidene chloride are isomers. Identify the correct statements.
(i) Both the compounds form same product on treatment with alcoholic KOH.
(ii) Both the compounds form same product on treatment with aq.NaOH.
(iii) Both the compounds form same product on reduction.
(iv) Both the compounds are optically active.
Which of the compounds will react faster in SN1 reaction with the –OH ion?
\[\ce{CH3-CH2-Cl}\] or \[\ce{C6H5-CH2-Cl}\]
Which of the following is the definition of chirality?
Which one of the following compounds is more reactive towards SN1 reaction?
Give reason for the following:
The product formed during SN1 reaction is a racemic mixture.
Give the mechanism of the following reaction:
\[\ce{CH3CH2OH ->[H2SO4][413 K] CH3CH2-O-CH2CH3 + H2O}\]
Identify the product in the following reaction: 
Discuss SN2 mechanism of methyl bromide using aqueous KOH.
Which alkyl halide from the following pair would you expect to react more rapidly by an SN2 mechanism? Explain your answer.
\[\begin{array}{cc}\ce{CH3CH2CHCH3}\\
\phantom{.....}|\\
\phantom{......}\ce{Br}\\
\end{array}\] or \[\begin{array}{cc}\phantom{.......}\ce{CH3}\\
\phantom{...}|\\
\ce{H3C - C - Br}\\
\phantom{...}|\\
\phantom{.......}\ce{CH3}\\
\end{array}\]
