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प्रश्न
How do polar solvents help in the first step in SN1 mechanism?
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उत्तर
The SN1 mechanism proceeds through the formation of carbocation. It involves breaking of C-halogen bond for which energy is obtained through the salvation of halide ion with the proton of the protic solvent. Thus, polar solvents help in ionisations step by stabilizing the ions by solvation.
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संबंधित प्रश्न
Write the structure of an isomer of compound C4H9Br which is most reactive towards SN1 reaction
Out of 
, which is more reactive towards SN1 reaction and why?
Which compound in the following pair will react faster in SN2 reaction with OH−?
CH3Br or CH3I
Write the structure of the major organic product in the following reaction:
\[\ce{CH3CH2Br + KCN ->[aq{.} ethanol]}\]
Write the structure of the major organic product in the following reaction:
\[\ce{CH3CH2CH2OH + SOCl2 ->}\]
Arrange the compounds of the following set in order of reactivity towards SN2 displacement:
2-Bromo-2-methylbutane, 1-Bromopentane, 2-Bromopentane
Arrange the compounds of the following set in order of reactivity towards SN2 displacement:
1-Bromobutane, 1-Bromo-2, 2-dimethylpropane, 1-Bromo-2-methylbutane, 1-Bromo-3-methylbutane
What happens when ethyl chloride is treated with aqueous KOH?
Answer the following question.
Write one stereochemical difference between SN1 and SN2 reactions.
In the reaction, \[\ce{R - X + NaOR' -> ROR’ + X}\] ( – ve ion). The main product formed is:
Which compound in the following pair reacts faster in SN2 reaction with OH–?
- CH3Br or CH3
- CH3Cl, (CH3)3CCl
Arrange the following organic compounds in descending order of their reactivity towards SN1 reaction.
C6H5CH2Br, C6H5CH(C6H5)Br, C6H5CH(CH3)Br, C6H5C(CH3)(C6H5)Br
Which of the following is optically inactive?
Which one of the following halogen compounds is difficult to be hydrolysed by SN1 mechanism?
Complete the following analogy:
Same molecular formula but different structures: A : : Non superimposable mirror images: B
Which of the statements are correct about above reaction?
(i) (a) and (e) both are nucleophiles.
(ii) In (c) carbon atom is sp3 hybridised.
(iii) In (c) carbon atom is sp2 hybridised.
(iv) (a) and (e) both are electrophiles.
Which of the following statements are correct about the kinetics of this reaction?
(i) The rate of reaction depends on the concentration of only (b).
(ii) The rate of reaction depends on concentration of both (a) and (b).
(iii) Molecularity of reaction is one.
(iv) Molecularity of reaction is two.
Which of the following is halogen exchange reaction?
Consider the reactions,
(i) \[\begin{array}{cc}
\phantom{}\ce{\underset{}{(CH3)2CH - CH2Br} ->[C2H5OH] \underset{}{(CH3)2CH - CH2OC2H5 + HBr}}\\
\end{array}\]
(ii) \[\begin{array}{cc}
\phantom{}\ce{\underset{}{(CH3)2CH - CH2Br} ->[C2H5O-] \underset{}{(CH3)2CH - CH2OC2H5 + Br-}}\\
\end{array}\]
The mechanisms of reactions (i) and (ii) are respectively:
The compound that will undergo SN1 reaction with the fastest rate is:
