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In the following pair of halogen compounds, which compound undergoes a faster SN1 reaction? Cl and Cl - Chemistry

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प्रश्न

In the following pair of halogen compounds, which compound undergoes a faster SN1 reaction?

लघु उत्तर
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उत्तर

The activity of halogen compounds in SN1 reaction depends on the stability of the carbocation formed due to ionization. The order of stability is tertiary > secondary > primary. Hence, 2° alkyl chloride is more active than 1° alkyl chloride. Hence, 2° alkyl chloride is more active in SN1 reaction.

reacts faster due to the greater stability of 2° carbocation than 1° carbocation.

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पाठ 6: Haloalkanes and Haloarenes - Intext Question [पृष्ठ १८६]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
पाठ 6 Haloalkanes and Haloarenes
Intext Question | Q 6.8 (ii) | पृष्ठ १८६

संबंधित प्रश्‍न

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\[\ce{CH3CH2CH2OH + SOCl2 ->}\]


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Write one stereochemical difference between SN1 and SN2 reactions.


In the reaction, \[\ce{R - X + NaOR' -> ROR’ + X}\] ( – ve ion). The main product formed is:


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  Reaction Product
I RX + AgCN RNC
II RX + KCN RCN
III RX + KNO2 \[\begin{array}{cc}
\phantom{.......}\ce{O}\\
\phantom{.....}/\\
\ce{R - N}\phantom{....}\\
\phantom{.....}\backslash\backslash\\
\phantom{.......}\ce{O}
\end{array}\]
IV RX + AgNO2 \[\ce{R-O-N=O}\]

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(i)

(ii)

CH3CH2CH2Cl

(iii)

\[\begin{array}{cc}
\ce{CH3}\phantom{..}\\
|\phantom{....}\\
\ce{CH3-CH-CH2Cl}
\end{array}\]

(iv)

\[\begin{array}{cc}
\phantom{..}\ce{H}\\
\phantom{..}|\\
\ce{CH3-C-Cl}\\
\phantom{..}|\\
\phantom{.....}\ce{C2H5}
\end{array}\]


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  Column I Column II
(i) (a) Nucleophilic aromatic substitution
(ii) \[\begin{array}{cc}
\ce{CH3 - CH = CH2 + HBr -> CH3 - CH - CH3}\\
\phantom{............................}|\phantom{}\\
\phantom{.............................}\ce{Br}\phantom{}
\end{array}\]
(b) Electrophilic aromatic substitution
(iii) (c) Saytzeff elimination
(iv) (d) Electrophilic addition
(v) \[\begin{array}{cc}
\ce{CH3  CH2 CH CH3 ->[alc.KOH] CH3  CH = CH CH3}\\
\phantom{}|\phantom{..........................}\\
\phantom{}\ce{Br}\phantom{........................}
\end{array}\]
(e) Nucleophilic substitution (SN1)

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HCI, Major product ______.


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