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प्रश्न
Out of
, which is more reactive towards SN1 reaction and why?
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उत्तर
Since formation of carbocation is the rate-determining step in the SN1 reaction, the stability of carbocation would determine its reactivity.
The order of stability of carbocation is as follows:
Tertiary > Secondary > Primary >Methyl
Here, 1-chloro-1-methylpropane would form secondary carbocation, while 1-chloro-2-methylpropane will form primary carbocation, which is less stable than secondary carbocation. Hence, reactivity towards the SN1 reaction would be higher for 1-chloro-1-methylpropane.
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संबंधित प्रश्न
How will you bring about the following conversion?
Toluene to benzyl alcohol
What happens when ethyl chloride is treated with aqueous KOH?
Given reasons: SN1 reactions are accompanied by racemization in optically active alkyl halides.
Identify 'A' in the following reaction -

(a) 2- Bromo-2 methylbutane
(b) 1 -Bromo-2,2-dimethylpropane
(c) 1 - Bromo - 3 -methylbutane
(d) 1 - Bromo- 2 -methylpropane
An organic molecule necessarily shows optical activity if it ____________.
Which of the following statements are correct about the kinetics of this reaction?

(i) The rate of reaction depends on the concentration of only (b).
(ii) The rate of reaction depends on concentration of both (a) and (b).
(iii) Molecularity of reaction is one.
(iv) Molecularity of reaction is two.
The number of chiral alcohol (s) with molecular formula C4H10O is ______.
Discuss SN2 mechanism of methyl bromide using aqueous KOH.
Discuss the mechanism of alkaline hydrolysis of methyl bromide.
Explain why Grignard reagents should be prepared under anhydrous conditions.
