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प्रश्न
Out of 
, which is more reactive towards SN1 reaction and why?
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उत्तर
Since formation of carbocation is the rate-determining step in the SN1 reaction, the stability of carbocation would determine its reactivity.
The order of stability of carbocation is as follows:
Tertiary > Secondary > Primary >Methyl
Here, 1-chloro-1-methylpropane would form secondary carbocation, while 1-chloro-2-methylpropane will form primary carbocation, which is less stable than secondary carbocation. Hence, reactivity towards the SN1 reaction would be higher for 1-chloro-1-methylpropane.
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संबंधित प्रश्न
Which compound in the following pair will react faster in SN2 reaction with OH−?
(CH3)3CCl or CH3Cl
Write the structure of the major organic product in the following reaction:
\[\ce{CH3CH(Br)CH2CH3 + NaOH ->[water]}\]
The stability order for carbocation is _______.
(A) 2° > 3° > 1°
(B) 3° > 2° > 1°
(C) 3° > 1° > 2°
(D) 1° > 3° > 2°
Which of the following is a primary halide?
Isopropyl chloride undergoes hydrolysis by:
The process of separation of a racemic modification into d and l-enantiomers is called ____________.
Among the following, the dissociation constant is highest for:
Complete the following analogy:
Same molecular formula but different structures: A : : Non superimposable mirror images: B
Which of the following statements are correct about the kinetics of this reaction?
(i) The rate of reaction depends on the concentration of only (b).
(ii) The rate of reaction depends on concentration of both (a) and (b).
(iii) Molecularity of reaction is one.
(iv) Molecularity of reaction is two.
The compound that will undergo SN1 reaction with the fastest rate is:
