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प्रश्न
Given reasons: SN1 reactions are accompanied by racemization in optically active alkyl halides.
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उत्तर
In SN1 reaction, formation of carbocation as an intermediate takes place. This carbocation has sp2-hybridised and planar structure. This planar carbocation is attacked by nucleophile from both the sides equally to form d and l isomers in equal proportion. Such products are called racemic mixture. Hence, SN1 reactions are accompanied by racemisation in optically active alkyl halides.
संबंधित प्रश्न
Given reasons: C–Cl bond length in chlorobenzene is shorter than C–Cl bond length in CH3–Cl.
How will you bring about the following conversion?
Toluene to benzyl alcohol
The order of reactivity of the given haloalkanes towards nucleophile is:
Most reactive halide towards SN1 reaction is ____________.
Which of the following compounds is optically active?
Give reason for the following:
The product formed during SN1 reaction is a racemic mixture.
Optical activity of an enantiomeric mixture is +12.6° and the specific rotation of (+) isomer is +30°. The optical purity is ______ %.
Convert bromoethane to propanamine.
Which of the following reactions is an example of nucleophilic substitution reaction?
Assertion (A):
undergoes SN2 reactions faster than
.
Reason (R): Iodine is a better leaving group because of its large size.
In the light of the above statements, choose the correct answer from the options given below:
