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प्रश्न
How is phenol converted into the following?
benzoquinone
Write the chemical reaction to convert phenol to benzoquinone.
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उत्तर
Phenol on oxidation with Na2Cr2O7 (chromic acid) in H2SO4, gives conjugated diketone known as benzoquinone, which is dark coloured.
संबंधित प्रश्न
Name the following compound according to IUPAC system.
\[\begin{array}{cc}
\phantom{............}\ce{CH2OH}\\
\phantom{......}|\\
\ce{CH3 - CH2 - CH - CH - CH - CH3}\\
\phantom{......}|\phantom{............}|\phantom{.}\\
\phantom{........}\ce{CH2Cl}\phantom{......}\ce{CH3}\phantom{}
\end{array}\]
Name the following compound according to IUPAC system.
\[\begin{array}{cc}
\phantom{........................}\ce{CH2OH}\\
\phantom{..................}|\\
\ce{CH3 - CH - CH2 - CH - CH - CH3}\\
\phantom{}|\phantom{.............}|\phantom{........}\\
\phantom{..}\ce{CH3}\phantom{..........}\ce{OH}\phantom{........}
\end{array}\]
Write IUPAC name of the following compound:
\[\begin{array}{cc}
\phantom{................}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
\phantom{...}\ce{CH3\phantom{.}}\phantom{..}\ce{OH}\phantom{...}\ce{CH3}
\end{array}\]
Write IUPAC name of the following compound:
\[\begin{array}{cc}
\ce{H3C - CH - CH2 - CH - CH - CH2 - CH3}\\
\phantom{}|\phantom{.............}|\phantom{......}|\phantom{.........}\\
\phantom{}\ce{OH}\phantom{..........}\ce{OH}\phantom{...}\ce{C2H5}\phantom{......}
\end{array}\]
Write IUPAC name of the following compound:
\[\begin{array}{cc}
\ce{HO - CH2 - CH - CH2 - OH}\\
|\phantom{..}\\
\ce{OH}
\end{array}\]
Write IUPAC name of the following compound:
Write IUPAC name of the following compound:
Write IUPAC name of the following compound:
Write IUPAC name of the following compound:
Write IUPAC name of the following compound:
\[\begin{array}{cc}
\ce{CH3 - O - CH2 - CH - CH3}\\
\phantom{..........}|\\
\phantom{............}\ce{CH3}
\end{array}\]
Write IUPAC name of the following compound:
C6H5 – O – C2H5
Write IUPAC name of the following compound:
C6H5 – O – C7H15(n−)
Write IUPAC name of the following compound:
\[\begin{array}{cc}
\ce{CH3 - CH2 - O - CH - CH2 - CH3}\\
\phantom{...}|\\
\phantom{.....}\ce{CH3}
\end{array}\]
Write structures of the compounds whose IUPAC names are as follows:
3-Chloromethylpentan-1-ol.
- Draw the structures of all isomeric alcohols of molecular formula C5H12O and give their IUPAC names.
- Classify the isomers of alcohols in the above question as primary, secondary and tertiary alcohols.
Give IUPAC name of the following ether:
\[\begin{array}{cc}
\ce{C2H5OCH2 - CH - CH3}\\
\phantom{.....}|\\
\phantom{.......}\ce{CH3}
\end{array}\]
Give IUPAC name of the following ether:
Ethylidene dichloride when boiled with aqueous solution of NaOH yields _______.
(A) formaldehyde
(B) acetaldehyde
(C) acetone
(D) ethyl methyl ketone
Natalite is a mixture of
(a) diethyl ether and methanol
(b) diethyl ether and ethanol
(c) dimethyl ether and methanol
(d) dimethyl ether and ethanol
Write the structure and IUPAC name of 'methyl-n-propyl ether'.
What is the action of hot HI on it?
How is phenol converted into the following?
Benzene
Write IUPAC name of the following compound (CH3)2 N − CH2CH3
Give reasons Fluoride ion has higher hydration enthalpy than chloride ion.
Write the IUPAC name of the following compound:
Write the structures of the products when Butan-2-ol reacts with CrO3
Write the structures of the products when Butan-2-ol reacts with SOCl2
Write the IUPAC name of the following :
How do you convert the Ethanal to Propanone
What.will be the product fonned when chlorobenzene is heated with sodium metal in the presence of dry ether?
Propanoic acid to ethylamine.
Write structural formulae for 3-Methoxyhexane
Write structural formula for Methyl vinyl ether.
Write structural formulae for 1-Ethylcyclohexanol.
Write structural formula for pentane-1,4-diol.
Write structural formulae for Cyclohex-2-en-1-ol.
Write IUPAC name of the following
\[\begin{array}{cc}\ce{CH3-CH-CH-CH2-OH}\\|\phantom{.....}|\phantom{.......}\\\ce{OH}\phantom{..}\ce{CH3}\phantom{.....}\end{array}\]
Write IUPAC names of the following
Write IUPAC names of the following
Glycerol is ____________.
Give IUPAC names of the following compound:
Give IUPAC names of the following compound:
\[\begin{array}{cc}
\phantom{..}\ce{H}\phantom{...}\ce{CH3}\phantom{.}\ce{H}\phantom{..}\\
\phantom{}|\phantom{....}|\phantom{....}|\phantom{}\\
\ce{H - C - C - C - H}\\
\phantom{}|\phantom{....}|\phantom{....}|\phantom{}\\
\phantom{.}\ce{H}\phantom{...}\ce{OH}\phantom{.}\ce{H}\phantom{.}\\
\end{array}\]
The compound HOCH2 – CH2OH is __________.
An example of a compound with functional group – O – is ____________.
Cresol has ____________.
Ethyl alcohol is industrially prepared from ethylene by:
Which of the following compounds is oxidised to prepare methyl ethyl ketone?
HBr reacts fastest with ____________.
IUPAC name of m-cresol is ____________.
1-Propanol and 2-propanol can be best distinguished by:
Which of the following is most acidic?
The major product formed by the reaction:
\[\begin{array}{cc}
\ce{CH3CH-CH2Br ->[CH3O^-][CH3OH] is}\\
|\phantom{................}\\
\ce{CH3}\phantom{.............}
\end{array}\]
\[\ce{HC ≡ CH ->[HgSO4][H2SO4] ->[CH3MgBr][H2O] ->[PBr3]}\]
The product of acid catalysed hydration of 2-phenylpropene is:
The heating of phenyl methyl ether with HI produces:
Which of the following gives a positive iodoform test?
\[\ce{Phenol ->[Zn, dust] 'X' ->[CH3Cl][Anhy. AlCl3] 'Y' ->[Alkaline][KMnO4] 'Z'}\]
The product ‘Z’ is:
Which of the following compounds will react with sodium hydroxide solution in water?
Which of the following reagents can be used to oxidise primary alcohols to aldehydes?
(i) \[\ce{CrO3}\] in anhydrous medium.
(ii) \[\ce{KMnO4}\] in acidic medium.
(iii) Pyridinium chlorochromate.
(iv) Heat in the presence of Cu at 573 K.
What happens when benzene diazonium chloride is heated with water?
Arrange the following compounds in decreasing order of acidity.
\[\ce{H2O, ROH, HC ≡ CH}\]
Explain why p-nitrophenol is more acidic than phenol.
Match the structures of the compounds given in Column I with the name of the compounds given in Column II.
| Column I | Column II | |
| (i) |  |
(a) Hydroquinone |
| (ii) |  |
(b) Phenetole |
| (iii) |  |
(c) Catechol |
| (iv) |  |
(d) o-Cresol |
| (v) |  |
(e) guinone |
| (vi) |  |
(f) Resorcinol |
| (g) Anisole |
Assertion: IUPAC name of the compound
\[\begin{array}{cc}
\ce{CH3 - CH - O - CH2 - CH2 - CH3}\\
|\phantom{....................}\\
\ce{CH3}\phantom{.................}
\end{array}\] is 2-Ethoxy-2-methylethane.
Reason: In IUPAC nomenclature, ether is regarded as hydrocarbon derivative in which a hydrogen atom is replaced by —OR or —OAr group [where R = alkyl group and Ar = aryl group]
Write complete reaction for the bromination of phenol in aqueous and non-aqueous medium.
Explain why Lewis acid is not required in bromination of phenol?
How can phenol be converted to aspirin?
Write the IUPAC name of the following compound.
Convert the following:
Ethyl alcohol into ethyl acetate.
Identify A and B in the following:
Write IUPAC name of the following compound:
\[\begin{array}{cc}
\phantom{................}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
\phantom{...}\ce{CH3}\phantom{..}\ce{OH}\phantom{...}\ce{CH3}
\end{array}\]
Draw structure of the following compound.
2-Methoxypropane
Draw structure of the following compound.
Prop-2-en-1-ol
Give the structures of Thiosulphuric acid and Peroxy monosulphuric acid.
Write the IUPAC name of the following compound:
\[\begin{array}{cc}
\phantom{..............}\ce{CH3}\\
\phantom{............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{.....}|\phantom{......}|\\
\phantom{...}\ce{CH3}\phantom{.}\ce{OH}\phantom{...}\ce{CH3}
\end{array}\]
Write IUPAC names of the following compounds:
\[\begin{array}{cc}
\phantom{...............}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
\phantom{...}\ce{CH3\phantom{...}OH\phantom{...}CH3}\\
\end{array}\]
Write IUPAC name of the following compound:
\[\begin{array}{cc}
\phantom{................}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
\phantom{...}\ce{CH3}\phantom{...}\ce{OH}\phantom{...}\ce{CH3}
\end{array}\]
Write the IUPAC name of the following compound:
\[\begin{array}{cc}
\phantom{...............}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
\phantom{...}\ce{CH3}\phantom{..}\ce{OH}\phantom{...}\ce{CH3}
\end{array}\]
