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What is the Action of Hot Hi on It? - Chemistry

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प्रश्न

What is the action of hot HI on it?

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उत्तर

Action of hot HI on methyl n-propyl ether:

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2015-2016 (July)

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संबंधित प्रश्न

What is metamerism? 


Explain metamerism with suitable examples of ethers


Write the IUPAC name of the given compound:


Name the following compound according to IUPAC system.

\[\begin{array}{cc}
\phantom{............}\ce{CH2OH}\\
\phantom{......}|\\
\ce{CH3 - CH2 - CH - CH - CH - CH3}\\
\phantom{......}|\phantom{............}|\phantom{.}\\
\phantom{........}\ce{CH2Cl}\phantom{......}\ce{CH3}\phantom{}
\end{array}\]


Name the following compound according to IUPAC system.

\[\begin{array}{cc}
\phantom{........................}\ce{CH2OH}\\
\phantom{..................}|\\
\ce{CH3 - CH - CH2 - CH - CH - CH3}\\
\phantom{}|\phantom{.............}|\phantom{........}\\
\phantom{..}\ce{CH3}\phantom{..........}\ce{OH}\phantom{........}
\end{array}\]


Name the following compound according to IUPAC system.


Name the following compound according to IUPAC system.

\[\begin{array}{cc}
\ce{H2C = CH - CH - CH2 - CH2 - CH3}\\
|\phantom{..........}\\
\ce{OH}\phantom{........}
\end{array}\]


Name the following compound according to IUPAC system.

\[\begin{array}{cc}
\ce{CH3 - C = C - CH2OH}\\
\phantom{}|\phantom{....}|\phantom{....}\\
\phantom{}\ce{CH3}\phantom{.}\ce{Br}\phantom{...}
\end{array}\]


Write IUPAC name of the following compound:

\[\begin{array}{cc}
\phantom{................}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
\phantom{...}\ce{CH3\phantom{.}}\phantom{..}\ce{OH}\phantom{...}\ce{CH3}
\end{array}\]


Write IUPAC name of the following compound:

\[\begin{array}{cc}
\ce{CH3 - CH - CH - CH3}\\
|\phantom{......}|\phantom{..}\\
\ce{OH}\phantom{...}\ce{OH}\phantom{}
\end{array}\]


Write IUPAC name of the following compound:

\[\begin{array}{cc}
\ce{HO - CH2 - CH - CH2 - OH}\\
|\phantom{..}\\
\ce{OH}
\end{array}\]


Write IUPAC name of the following compound:


Write IUPAC name of the following compound:


Write IUPAC name of the following compound:

\[\begin{array}{cc}
\ce{CH3 - O - CH2 - CH - CH3}\\
\phantom{..........}|\\
\phantom{............}\ce{CH3}
\end{array}\]


Write IUPAC name of the following compound:

C6H5 – O – C2H5


Write structures of the compounds whose IUPAC names are as follows:

3-Chloromethylpentan-1-ol.


  1. Draw the structures of all isomeric alcohols of molecular formula C5H12O and give their IUPAC names.
  2. Classify the isomers of alcohols in the above question as primary, secondary and tertiary alcohols.

Give IUPAC name of the following ether:

\[\begin{array}{cc}
\ce{C2H5OCH2 - CH - CH3}\\
\phantom{.....}|\\
\phantom{.......}\ce{CH3}
\end{array}\]


Give IUPAC name of the following ether:

CH3OCH2CH2Cl


Give IUPAC name of the following ether:

CH3CH2CH2OCH3


Give IUPAC name of the following ether:


Which of the following compounds is NOT prepared by the action of alcoholic NI3 on alkyl halide?

(a) CH3NH2

(b) CH3- CH2- NH2

(c) CH3 - CH2 - CH2 - NH2

(d) (CH3)C- NH2


3-Methylbutane-2-ol on heating with HI gives ______


How is phenol converted into the following?

benzoquinone


How is phenol converted into the following?

picric acid


Write the IUPAC name of the following compound: 


Write the structures of the products when Butan-2-ol reacts with CrO3


Write the structures of the products when Butan-2-ol reacts with SOCl2


How do you convert the Ethanal to Propanone


In the dehydration of alcohols to alkenes by heating with concentrated sulphuric acid, the initiation step is:

(1) formation of carbonation

(2) formation of an ester

(3) protonation of the alcohol molecule

(4) elimination of water


Propanoic acid to ethylamine.


Write structural formula for Methyl vinyl ether.


Write structural formulae for 1-Ethylcyclohexanol.


Write structural formula for pentane-1,4-diol.


Write structural formulae for Cyclohex-2-en-1-ol.


Write IUPAC name of the following


Write IUPAC name of the following

\[\begin{array}{cc}\ce{CH3-CH-CH-CH2-OH}\\|\phantom{.....}|\phantom{.......}\\\ce{OH}\phantom{..}\ce{CH3}\phantom{.....}\end{array}\]


Write IUPAC names of the following


In a carbinol system of nomenclature tert.butyl alcohol is named as _______________


Glycerol is ____________.


Isopropyl alcohol on oxidation forms:


Give IUPAC names of the following compound:


C6H5OCH2CH3 is called:


3-methylphenol is called ____________.


One of the following is not a dihydroxy derivative of benzene.


An example of a compound with functional group – O – is ____________.


Butane-2-ol is ____________.


Cresol has ____________.


Ethyl alcohol is industrially prepared from ethylene by:


HBr reacts fastest with ____________.


Ethylene reacts with Baeyer’s reagent to give ______.


When ethyl alcohol reacts with acetic acid, the products formed are:


1-Propanol and 2-propanol can be best distinguished by:


Which of the following is most acidic?


\[\ce{HC ≡ CH ->[HgSO4][H2SO4] ->[CH3MgBr][H2O] ->[PBr3]}\]


The product of acid catalysed hydration of 2-phenylpropene is:


The heating of phenyl methyl ether with HI produces:


\[\ce{Phenol ->[Zn, dust] 'X' ->[CH3Cl][Anhy. AlCl3] 'Y' ->[Alkaline][KMnO4] 'Z'}\]

The product ‘Z’ is:


Among the following sets of reactants which one produces anisole?


IUPAC name of m-cresol is ______.


IUPAC name of the compound \[\begin{array}{cc}
\ce{CH3 - CH - OCH3}\\
\phantom{}|\phantom{....}\\
\phantom{}\ce{CH3}\phantom{..}
\end{array}\] is ______.


Which of the following compounds will react with sodium hydroxide solution in water?


Which of the following reagents can be used to oxidise primary alcohols to aldehydes?

(i) \[\ce{CrO3}\] in anhydrous medium.

(ii) \[\ce{KMnO4}\] in acidic medium.

(iii) Pyridinium chlorochromate.

(iv) Heat in the presence of Cu at 573 K.


Write the IUPAC name of the compound given below.

\[\begin{array}{cc}
\phantom{}\ce{CH3 - CH2 - C = C - OH}\\
\phantom{........}|\phantom{....}|\phantom{}\\
\phantom{..............}\ce{CH3 CH2OH}
\end{array}\]


Arrange the following compounds in decreasing order of acidity.

\[\ce{H2O, ROH, HC ≡ CH}\]


Match the structures of the compounds given in Column I with the name of the compounds given in Column II.

  Column I Column II
(i) (a) Hydroquinone
(ii) (b) Phenetole
(iii) (c) Catechol
(iv) (d) o-Cresol
(v) (e) guinone
(vi) (f) Resorcinol
    (g) Anisole

Match the starting materials given in Column I with the products formed by these (Column II) in the reaction with HI.

  Column I   Column II
(i) CH3—O—CH3 (a)
(ii) \[\begin{array}{cc}
\ce{CH3}\phantom{..................}\\
\backslash\phantom{.............}\\
\ce{CH-O-CH3}\\
/\phantom{..............}\\
\ce{CH3}\phantom{..................}
\end{array}\]
(b) \[\begin{array}{cc}
\ce{CH3}\phantom{....}\\
|\phantom{.......}\\
\ce{CH3-C-I + CH3OH}\\
|\phantom{.......}\\
\ce{CH3}\phantom{....}
\end{array}\]
(iii) \[\begin{array}{cc}
\ce{CH3}\phantom{.}\\
|\phantom{....}\\
\ce{H3C-C-O-CH3}\\
|\phantom{....}\\
\ce{CH3}\phantom{..}
\end{array}\]
(c)
(iv) (d) CH3—OH + CH3—I
    (e) \[\begin{array}{cc}
\ce{CH3}\phantom{.....................}\\
\backslash\phantom{.................}\\
\ce{CH-OH + CH3I}\\
/\phantom{.................}\\
\ce{CH3}\phantom{.....................}
\end{array}\]
    (f) \[\begin{array}{cc}
\ce{CH3}\phantom{.....................}\\
\backslash\phantom{.................}\\
\ce{CH-I + CH3OH}\\
/\phantom{.................}\\
\ce{CH3}\phantom{.....................}
\end{array}\]
    (g) \[\begin{array}{cc}
\ce{CH3}\phantom{....}\\
|\phantom{.......}\\
\ce{CH3-C-OH + CH3I}\\
|\phantom{.......}\\
\ce{CH3}\phantom{....}
\end{array}\]

Assertion: Addition reaction of water to but-1-ene in acidic medium yields butan-1-ol.

Reason: Addition of water in acidic medium proceeds through the formation of primary carbocation.


Assertion: p-nitrophenol is more acidic than phenol.

Reason: Nitro group helps in the stabilisation of the phenoxide ion by dispersal of negative charge due to resonance.


Assertion: IUPAC name of the compound

\[\begin{array}{cc}
\ce{CH3 - CH - O - CH2 - CH2 - CH3}\\  
|\phantom{....................}\\
\ce{CH3}\phantom{.................}
\end{array}\] is 2-Ethoxy-2-methylethane.

Reason: In IUPAC nomenclature, ether is regarded as hydrocarbon derivative in which a hydrogen atom is replaced by —OR or —OAr group [where R = alkyl group and Ar = aryl group]


Assertion: Like bromination of benzene, bromination of phenol is also carried out in the presence of Lewis acid.

Reason: Lewis acid polarises the bromine molecule.


Assertion: Phenol forms 2, 4, 6 – tribromophenol on treatment with \[\ce{Br2}\] in carbon disulphide at 273 K.

Reason: Bromine polarises in carbon disulphide.


Assertion: Phenols give o- and p-nitrophenol on nitration with conc. \[\ce{HNO3}\] and \[\ce{H2SO4}\] mixture.

Reason: –OH group in phenol is o–, p– directing.


Write the IUPAC name of the following compound.


Convert the following:

Ethyl alcohol into ethyl acetate.


How are the following conversions carried out?

Methyl magnesium bromide→2-Methylpropan-2-ol.


Write IUPAC name of the following compound:

\[\begin{array}{cc}
\phantom{................}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
\phantom{...}\ce{CH3}\phantom{..}\ce{OH}\phantom{...}\ce{CH3}
\end{array}\]


Draw structure of the following compound.

2. 5-Diethylphenol


Draw structure of the following compound.

Prop-2-en-1-ol


Write structural formulae for:

Salicylic acid


The IUPAC name of is ______.


Write the IUPAC name.

\[\begin{array}{cc}
\phantom{................}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C  -CH3}\\
\phantom{.}|\phantom{......}|\phantom{......}|\\
\phantom{....}\ce{CH3\phantom{...}\ce{OH}\phantom{...}\ce{CH3}}\
\end{array}\]


Write IUPAC name of the following compound:

\[\begin{array}{cc}
\phantom{................}\ce{CH3}\\
\phantom{.............}|\\
\ce{CH3 - CH - CH - C - CH3}\\
|\phantom{......}|\phantom{......}|\\
\phantom{...}\ce{CH3}\phantom{...}\ce{OH}\phantom{...}\ce{CH3}
\end{array}\]


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