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What are amines? - Chemistry

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What are amines?

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Solution

Amines are nitrogen-containing organic compounds having basic character.

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Chapter 13: Amines - Exercises [Page 297]

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Balbharati Chemistry [English] Standard 12 Maharashtra State Board
Chapter 13 Amines
Exercises | Q 4.2 | Page 297

RELATED QUESTIONS

In the following 

The compound ‘B’ is _______.
(A) Propan–1–amine

(B) Propan–2–amine

(C) Isopropylamine

(D) Dimethylamine


Give reasons for the following:

CH3NH2 is more basis than C6H5NH2.


Choose the most correct option.

The hybridisation of nitrogen in primary amine is ____________.


Isobutylamine is an example of ______.


Choose the most correct option.

Which type of amine does produce N2 when treated with HNO2?


Choose the most correct option.

Identify ‘B’ in the following reactions

\[\ce{CH3 - C ≡ N ->[Na/C2H5OH] A ->[NaNO2/dilHCl]B}\]


How are amines classified?


Write the number of moles of ethanoyl chloride required for complete acylation of N, N-dimethylaniline.


Assertion: Acetamide on reaction with KOH and bromine gives acetic acid.

Reason: Bromine catalyses hydrolysis of acetamide.


\[\ce{Aniline + benzoylchloride ->[NaOH] C6H5 - NH - COC6H5}\] this reaction is known as ____________.


The order of basic strength for methyl substituted amines in aqueous solution is ____________.


\[\ce{C6H5NO2 ->[Fe/HCl] A ->[NaNO2/HCl][273 K] B ->[H2O][283 K] C}\] ‘C’ is:


Which of the following amines does not undergo acetylation?


Which one of the following is most basic?


IUPAC name for the amine is:

\[\begin{array}{cc}
\phantom{.}\ce{CH3}\\
|\phantom{..}\\
\ce{CH3 - N - C - CH2 - CH3}\\
\phantom{.}|\phantom{.....}|\phantom{........}\\
\phantom{}\ce{CH3}\phantom{..}\ce{C2H5}\phantom{....}
\end{array}\]


How will you convert nitrobenzene into m-nitro aniline?


Write a short note on the following.

Ammonolysis


Write a short note on the following:

Gabriel phthalimide synthesis


Write a short note on the following.

Schotten-Baumann reaction


Write a short note on the following.

Carbylamine reaction


How will you distinguish between primary secondary and tertiary aliphatic amines?


Account for the following.

pKb of aniline is more than that of methylamine.


Account for the following.

Although amino group is o- and p-directing in aromatic electrophilic substitution reactions, aniline on nitration gives a substantial amount of m-nitroaniline.


Arrange the following.

In increasing order of boiling point C6H5OH, (CH3)2NH, C2H5NH2.


Arrange the following.

In decreasing order of the pKb values C2H5NH2, C6H5NHCH3, (C2H)2NH and CH3NH2.


Arrange the following.

Increasing order of basic strength C6H5NH2, C6H5N(CH3)2, (C2H5)2NH and CH3NH2.


How will you prepare propan-1-amine from butane nitrile?


How will you prepare propan-1-amine from propanamide?


How will you prepare propan-1-amine from 1-nitropropane?


Identify A, B and C.

\[\ce{CH3 - NO2 ->[LiAlH4] A ->[2CH3CH2Br] B ->[H2SO4] C}\]


How will you convert diethylamine into N-nitrosodiethylamine?


(C2H5)2CHNH2. The following amine can be classified as:


Arrange the following in the increasing order of their basic strength:

C2H5NH2, C6H5NH2, (C2H5)2NH


The reaction of NHO2 with 'A' gives quartering ammonium salt. A is which of the following?


Classify the following amine as primary, secondary or tertiary:


Classify the following amine as primary, secondary or tertiary:


Which among the following is the strongest Bronsted base?


Assertion A: Aniline on nitration yields ortho, meta and para nitro derivatives of aniline.

Reason R: Nitrating mixture is a storng acidic mixture.
In the light of the above statements, choose the correct answer from the options given below: 


Arrange the increasing order of solubility in water.

\[\ce{C2H5Cl, C2H5NH2, C2H5OH}\]


Write short note on the following:

Ammonolysis


Write short notes on the following

Ammonolysis


Write a short note on the following.

Ammonolysis


Name the distinguishing test for differentiating 1° amine from 2° and 3° amine.


Write short note on the following.

Ammonolysis


Define Amines.


Account for the following:

Aniline does not undergo Friedel-Crafts reaction.


Write short note on Ammonolysis.


Write a short note on the following.

Ammonolysis


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