English
Karnataka Board PUCPUC Science 2nd PUC Class 12

The decomposition of hydrocarbon follows the equation k = (4.5 ร— 10^11โข ๐‘ โˆ’1)โข ๐‘’^โˆ’28000โข๐พ/๐‘‡ Calculate Ea.

Advertisements
Advertisements

Question

The decomposition of hydrocarbon follows the equation

k = `(4.5 xx 10^11 s^-1) e^(-28000 K//T)`

Calculate Ea.

Numerical
Advertisements

Solution

According to the Arrhenius equation, k = `Ae^((-E_a)/(RT))`

∴ `-E_a/(RT) = -(28000 K)/T`

Ea = 28000 K × R

= 28000 K × 8.314 JK−1 mol1

= 232.79 kJ mol−1

shaalaa.com
  Is there an error in this question or solution?
Chapter 3: Chemical Kinetics - 'NCERT TEXT-BOOK' Exercises [Page 282]

APPEARS IN

Nootan Chemistry [English] Class 12 ISC
Chapter 3 Chemical Kinetics
'NCERT TEXT-BOOK' Exercises | Q 4.26 | Page 282
NCERT Chemistry Part 1 and 2 [English] Class 12
Chapter 3 Chemical Kinetics
Exercises | Q 3.26 | Page 87

RELATED QUESTIONS

 

Consider the reaction

`3I_((aq))^-) +S_2O_8^(2-)->I_(3(aq))^-) + 2S_2O_4^(2-)`

At particular time t, `(d[SO_4^(2-)])/dt=2.2xx10^(-2)"M/s"`

What are the values of the following at the same time?

a. `-(d[I^-])/dt`

b. `-(d[S_2O_8^(2-)])/dt`

c. `-(d[I_3^-])/dt`

 

 

The rate constant of a first order reaction increases from 4 × 10−2 to 8 × 10−2 when the temperature changes from 27°C to 37°C. Calculate the energy of activation (Ea). (log 2 = 0.301, log 3 = 0.4771, log 4 = 0.6021)


The rate constant for the decomposition of N2O5 at various temperatures is given below:

T/°C 0 20 40 60 80
105 × k/s−1 0.0787 1.70 25.7 178 2140

Draw a graph between ln k and `1/T` and calculate the values of A and Ea. Predict the rate constant at 30º and 50ºC.


The decomposition of A into product has value of k as 4.5 × 103 s−1 at 10°C and energy of activation 60 kJ mol−1. At what temperature would k be 1.5 × 104 s−1?


In the Arrhenius equation for a first order reaction, the values of ‘A’ of ‘Ea’ are 4 × 1013 sec−1 and 98.6 kJ mol1 respectively. At what temperature will its half life period be 10 minutes?

[R = 8.314 J K1 mol1]


Explain the following terms :

Half life period of a reaction (t1/2)

 

 

The chemical reaction in which reactants require high amount of activation energy are generally ____________.


Consider figure and mark the correct option.


Which of the following graphs represents exothermic reaction?

(a)  

(b)  

(c)  


Mark the incorrect statements:

(i) Catalyst provides an alternative pathway to reaction mechanism.

(ii) Catalyst raises the activation energy.

(iii) Catalyst lowers the activation energy.

(iv) Catalyst alters enthalpy change of the reaction.


The reaction between \[\ce{H2(g)}\] and \[\ce{O2(g)}\] is highly feasible yet allowing the gases to stand at room temperature in the same vessel does not lead to the formation of water. Explain.


Why does the rate of a reaction increase with rise in temperature?


The rate constant for a reaction is 1.5 × 10–7 sec–1 at 50°C. What is the value of activation energy?


The slope of Arrhenius Plot `("In"  "k"  "v"//"s" 1/"T")` of first-order reaction is −5 × 103 K. The value of Ea of the reaction is. Choose the correct option for your answer. [Given R = 8.314 JK−1mol−1]


The activation energy of one of the reactions in a biochemical process is 532611 J mol–1. When the temperature falls from 310 K to 300 K, the change in rate constant observed is k300 = x × 10–3 k310. The value of x is ______.

[Given: ln 10 = 2.3, R = 8.3 J K–1 mol–1]


The equation k = `(6.5 xx 10^12 "s"^(-1))"e"^(- 26000 " K"//"T")` is followed for the decomposition of compound A. The activation energy for the reaction is ______ kJ mol-1. (Nearest integer) (Given: R = 8.314 JK-1 mol-1)


A schematic plot of ln Keq versus inverse of temperature for a reaction is shown below

The reaction must be:


It is generally observed that the rate of a chemical reaction becomes double with every 10°C rise in temperature. If the generalisation holds true for a reaction in the temperature range of 298 K to 308 K, what would be the value of activation energy (Ea) for the reaction?


Share
Notifications

Englishเคนเคฟเค‚เคฆเฅ€เคฎเคฐเคพเค เฅ€


      Forgot password?
Use app×