Advertisements
Advertisements
प्रश्न
The decomposition of hydrocarbon follows the equation
k = `(4.5 xx 10^11 s^-1) e^(-28000 K//T)`
Calculate Ea.
Advertisements
उत्तर
According to the Arrhenius equation, k = `Ae^((-E_a)/(RT))`
∴ `-E_a/(RT) = -(28000 K)/T`
Ea = 28000 K × R
= 28000 K × 8.314 JK−1 mol−1
= 232.79 kJ mol−1
संबंधित प्रश्न
The rate constant for the first-order decomposition of H2O2 is given by the following equation:
`logk=14.2-(1.0xx10^4)/TK`
Calculate Ea for this reaction and rate constant k if its half-life period be 200 minutes.
(Given: R = 8.314 JK–1 mol–1)
The rate constant of a first order reaction increases from 2 × 10−2 to 4 × 10−2 when the temperature changes from 300 K to 310 K. Calculate the energy of activation (Ea).
(log 2 = 0.301, log 3 = 0.4771, log 4 = 0.6021)
The rate of the chemical reaction doubles for an increase of 10 K in absolute temperature from 298 K. Calculate Ea.
The rate constant for the decomposition of N2O5 at various temperatures is given below:
| T/°C | 0 | 20 | 40 | 60 | 80 |
| 105 × k/s−1 | 0.0787 | 1.70 | 25.7 | 178 | 2140 |
Draw a graph between ln k and `1/T` and calculate the values of A and Ea. Predict the rate constant at 30º and 50ºC.
Consider a certain reaction \[\ce{A -> Products}\] with k = 2.0 × 10−2 s−1. Calculate the concentration of A remaining after 100 s if the initial concentration of A is 1.0 mol L−1.
Define activation energy.
What is the effect of adding a catalyst on Activation energy (Ea)
The reaction between \[\ce{H2(g)}\] and \[\ce{O2(g)}\] is highly feasible yet allowing the gases to stand at room temperature in the same vessel does not lead to the formation of water. Explain.
Why does the rate of a reaction increase with rise in temperature?
Why in the redox titration of \[\ce{KMnO4}\] vs oxalic acid, we heat oxalic acid solution before starting the titration?
What happens to most probable kinetic energy and the energy of activation with increase in temperature?
Total number of vibrational degrees of freedom present in CO2 molecule is
For an endothermic reaction energy of activation is Ea and enthalpy of reaction ΔH (both of there in KJ moI–1) minimum value of Ea will be ______.
In respect of the eqn k = \[\ce{Ae^{{-E_a}/{RT}}}\] in chemical kinetics, which one of the following statement is correct?
The activation energy of one of the reactions in a biochemical process is 532611 J mol–1. When the temperature falls from 310 K to 300 K, the change in rate constant observed is k300 = x × 10–3 k310. The value of x is ______.
[Given: ln 10 = 2.3, R = 8.3 J K–1 mol–1]
The equation k = `(6.5 xx 10^12 "s"^(-1))"e"^(- 26000 " K"//"T")` is followed for the decomposition of compound A. The activation energy for the reaction is ______ kJ mol-1. (Nearest integer) (Given: R = 8.314 JK-1 mol-1)
A schematic plot of ln Keq versus inverse of temperature for a reaction is shown below

The reaction must be:
A first-order reaction is 50% complete in 30 minutes at 300 K and in 10 minutes at 320 K. Calculate activation energy (Ea) for the reaction. [R = 8.314 J K−1 mol−1]
[Given: log 2 = 0.3010, log 3 = 0.4771, log 4 = 0.6021]
The rate of a reaction quadruples when temperature changes from 27°C to 57°C calculate the energy of activation.
(Given: R = 8. 314 J K−1 mol−1, log 4 = 0.6021)
