English
Karnataka Board PUCPUC Science 2nd PUC Class 12

Draw all the isomers (geometrical and optical) of [Co(NH3)2Cl2(en)]+. - Chemistry

Advertisements
Advertisements

Questions

Draw all the isomers (geometrical and optical) of [Co(NH3)2Cl2(en)]+.

Draw all the isomers (geometrical and optical) of [CoCl2(en)(NH3)2]+.

Chemical Equations/Structures
Advertisements

Solution

(i)

(ii)

(iii)

(iv)

All are asymmetric. Hence, all will show optical isomerism, i.e. d(+) and l(-) forms, which are non-superimposable mirror images.

shaalaa.com
Isomerism in Coordination Compounds - Stereoisomerism
  Is there an error in this question or solution?
Chapter 5: Coordinate Compounds - Exercises [Page 139]

APPEARS IN

NCERT Chemistry Part 1 and 2 [English] Class 12
Chapter 5 Coordinate Compounds
Exercises | Q 5.11 (iii) | Page 139

RELATED QUESTIONS

Draw one of the geometrical isomers of the complex [Pt (en)2Cl2] +2 which is optically inactive


Draw the geometrical isomers of complex \[\ce{[Co(en)2Cl2]+}\].


Indicate the types of isomerism exhibited by the following complex and draw the structures for these isomers:

[Co(en)3]Cl3


Indicate the types of isomerism exhibited by the following complex and draw the structures for these isomers:

[Co(NH3)5(NO2)](NO3)2


Indicate the types of isomerism exhibited by the following complex and draw the structure for this isomer:

[Pt(NH3)(H2O)Cl2]


How many geometrical isomers are possible in the following coordination entity? 

[Cr(C2O4)3]3−


How many geometrical isomers are possible in the following coordination entity? 

[Co(NH3)3Cl3]


Draw the structure of optical isomers of [PtCl2(en)2]2+.


Draw all the isomers (geometrical and optical) of [CoCl2(en)2]+.


Draw all the isomers (geometrical and optical) of [Co(NH3)Cl(en)2]2+.


Write the structures of optical isomers of the complex ion [Co(en)2Cl2]+.


Answer the following question.
Write IUPAC name of the complex [Pt(en)2CI2]. Draw structures of geometrical isomers for this complex.


Name the type of isomerism shown by the following pair of compounds:

[Cr(NH3)5Br]SO4 and [Cr(NH3)5SO4]Br


Draw the geometrical isomers of [Co(en)2Cl2]2+. Which geometrical isomer of [Co(en)2Cl2]2+ is not optically active and why?


Assertion (A): Trans [CrCl2(ox)2]3− shows optical isomerism.

Reason (R): Optical isomerism is common in octahedral complexes involving didentate ligands.


Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers: 

[Pt(NH3)(H2O)Cl2 ]


Indicate the type of isomerism exhibited by the following complex and draw the structure for this isomer: \[\ce{[Pt(NH3)(H2O)Cl2]}\]


Indicate the types of isomerism exhibited by the following complexes and draw the structure for these isomer:

\[\ce{[Pt(NH3)(H2O)Cl2]}\]


Indicate the types of isomerism exhibited by the following complex and draw the structure for this isomer:

\[\ce{[Pt(NH3)(H2O)Cl2]}\]


Indicate the types of isomerism exhibited by the following complex and draw the structure for this isomer:

\[\ce{[Pt(NH3)(H2O)Cl2]}\]


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×