Advertisements
Advertisements
Question
Write all the geometrical isomers of [Pt(NH3)(Br)(Cl)(py)] and how many of these will exhibit optical isomers?
Advertisements
Solution
| \[\begin{array}{cc} \ce{NH3}\phantom{.....}\ce{Br}\\ \phantom{.}\backslash\phantom{...}/\\ \ce{Pt}\\ /\phantom{...}\backslash\\ \ce{Cl}\phantom{.....}\ce{Py}\phantom{.} \end{array}\] |
\[\begin{array}{cc} \ce{H3N}\phantom{.....}\ce{Br}\phantom{.}\\ \phantom{.}\backslash\phantom{...}/\\ \ce{Pt}\\ /\phantom{...}\backslash\\ \ce{Py}\phantom{.....}\ce{Cl}\ \end{array}\] |
\[\begin{array}{cc} \ce{H3N}\phantom{.....}\ce{Cl}\phantom{.}\\ \phantom{.}\backslash\phantom{...}/\\ \ce{Pt}\\ /\phantom{...}\backslash\\ \ce{Py}\phantom{.....}\ce{Br}\ \end{array}\] |
Square planar complexes never show optical isomerism because of the plane of symmetry present in this case.
APPEARS IN
RELATED QUESTIONS
Explain cationic complexes and anionic complexes of co-ordination compounds.
When a coordination compound CoCl3.6NH3 is mixed with AgNO3, 3 moles of AgCl are precipitated per mole of the compound. Write the structural formula of the coordination compound.
Draw one of the geometrical isomers of the complex [Pt (en)2Cl2] +2 which is optically inactive
Draw one of the geometrical isomers of the complex [Pt(en)2Cl2]2+ which is optically active.
Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:
[Pt(NH3)(H2O)Cl2]
How many geometrical isomers are possible in the following coordination entity?
[Co(NH3)3Cl3]
Draw the structure of optical isomers of [Cr(C2O4)3]3−.
Draw the structure of optical isomers of [Cr(NH3)2Cl2(en)]+.
What type of isomers are `[Co(NH_3)_5Br]SO_4`and `[Co(NH_3)_5SO_4]Br`?. Give a chemical test to distinguish between them.
Why is Butan-1-ol optically inactive but Butan-2-ol is optically active?
Draw the geometrical isomers of complex [Pt(en)2Cl2]2+.
Name the type of isomerism that the compound with molecular formula C3H6O2 exhibits. Represent the isomers.
Write the IUPAC name of [Co(en)2Cl2]+ ion.
The IUPAC name for [CoCl(NO2)(en)2]Cl is ____________.
Identify the optically active compounds from the following:
(i) \[\ce{[Co(en)3]^{3+}}\]
(ii) \[\ce{[trans - [Co(en)2Cl2]^+}\]
(iii) \[\ce{cis - [Co(en)2Cl2]^+}\]
(iv) \[\ce{[Cr(NH3)5Cl]}\]
Assertion (A): Trans [CrCl2(ox)2]3− shows optical isomerism.
Reason (R): Optical isomerism is common in octahedral complexes involving didentate ligands.
Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers:
[Pt(NH3)(H2O)Cl2 ]
Indicate the type of isomerism exhibited by the following complex and draw the structure for this isomer:
[Pt(NH3)(H2O)Cl2]
Indicate the types of isomerism exhibited by the following complex and draw the structure for this isomer:
\[\ce{[Pt(NH3)(H2O)Cl2]}\]
