Advertisements
Advertisements
प्रश्न
Write all the geometrical isomers of [Pt(NH3)(Br)(Cl)(py)] and how many of these will exhibit optical isomers?
Advertisements
उत्तर
| \[\begin{array}{cc} \ce{NH3}\phantom{.....}\ce{Br}\\ \phantom{.}\backslash\phantom{...}/\\ \ce{Pt}\\ /\phantom{...}\backslash\\ \ce{Cl}\phantom{.....}\ce{Py}\phantom{.} \end{array}\] |
\[\begin{array}{cc} \ce{H3N}\phantom{.....}\ce{Br}\phantom{.}\\ \phantom{.}\backslash\phantom{...}/\\ \ce{Pt}\\ /\phantom{...}\backslash\\ \ce{Py}\phantom{.....}\ce{Cl}\ \end{array}\] |
\[\begin{array}{cc} \ce{H3N}\phantom{.....}\ce{Cl}\phantom{.}\\ \phantom{.}\backslash\phantom{...}/\\ \ce{Pt}\\ /\phantom{...}\backslash\\ \ce{Py}\phantom{.....}\ce{Br}\ \end{array}\] |
Square planar complexes never show optical isomerism because of the plane of symmetry present in this case.
APPEARS IN
संबंधित प्रश्न
Draw the geometrical isomers of complex [Pt(NH3)2Cl2].
Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:
K[Cr(H2O)2(C2O4)2]
Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:
[Co(NH3)5(NO2)](NO3)2
Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:
[Pt(NH3)(H2O)Cl2]
Draw all the isomers (geometrical and optical) of [Co(NH3)2Cl2(en)]+.
Why is Butan-1-ol optically inactive but Butan-2-ol is optically active?
Draw the geometrical isomers of complex [Pt(en)2Cl2]2+.
The IUPAC name for [CoCl(NO2)(en)2]Cl is ____________.
Identify the optically active compounds from the following:
(i) \[\ce{[Co(en)3]^{3+}}\]
(ii) \[\ce{[trans - [Co(en)2Cl2]^+}\]
(iii) \[\ce{cis - [Co(en)2Cl2]^+}\]
(iv) \[\ce{[Cr(NH3)5Cl]}\]
Draw the geometrical isomers of [Co(en)2Cl2]2+. Which geometrical isomer of [Co(en)2Cl2]2+ is not optically active and why?
Which of the following molecules has a chiral centre correctly labelled with an asterisk (*)?
Assertion (A): Trans [CrCl2(ox)2]3− shows optical isomerism.
Reason (R): Optical isomerism is common in octahedral complexes involving didentate ligands.
Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers:
[Pt(NH3)(H2O)Cl2 ]
Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers: [Pt(NH3)(H2O)Cl2]
Assertion: Addition of bromine water to 1-butene gives two optical isomers.
Reason: The product formed contains two asymmetric carbon atoms.
Indicate the types of isomerism exhibited by the following complex and draw the structure for these isomer: \[\ce{[Pt(NH3)(H2O)Cl2]}\]
Indicate the types of isomerism exhibited by the following complex and draw the structure for this isomer:
\[\ce{[Pt(NH3)(H2O)Cl2]}\]
