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प्रश्न
Draw all the isomers (geometrical and optical) of [CoCl2(en)2]+.
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उत्तर
trans [CoCl2(en)2]+
cis [CoCl2(en)2]+ optical isomers (d and l)
संबंधित प्रश्न
Explain cationic complexes and anionic complexes of co-ordination compounds.
Draw one of the geometrical isomers of the complex [Pt (en)2Cl2] +2 which is optically inactive
What type of isomerism is exhibited by the complex [Co(en)3]3+?
(en = ethane-1,2-diamine)
Define the following term:
Anomers
Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:
K[Cr(H2O)2(C2O4)2]
Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:
[Co(NH3)5(NO2)](NO3)2
How many geometrical isomers are possible in the following coordination entity?
[Cr(C2O4)3]3−
Write the structures of optical isomers of the complex ion [Co(en)2Cl2]+.
Name the type of isomerism exhibited by the following pairs of compound:
(1) (C2H5)2NH and CH3-NH-C3H7
(2) 1 – butanol and 2 methyl-1 -propanol.
Answer the following question.
Write IUPAC name of the complex [Pt(en)2CI2]. Draw structures of geometrical isomers for this complex.
Which one of the following complexes shows optical isomerism? (en = ethylenediamine)
Draw the geometrical isomers of [Co(en)2Cl2]2+. Which geometrical isomer of [Co(en)2Cl2]2+ is not optically active and why?
Which of the following molecules has a chiral centre correctly labelled with an asterisk (*)?
Assertion (A): Trans [CrCl2(ox)2]3− shows optical isomerism.
Reason (R): Optical isomerism is common in octahedral complexes involving didentate ligands.
Assertion: Addition of bromine water to 1-butene gives two optical isomers.
Reason: The product formed contains two asymmetric carbon atoms.
Indicate the type of isomerism exhibited by the following complex and draw the structure for this isomer:
[Pt(NH3)(H2O)Cl2]
Indicate the types of isomerism exhibited by the following complex and draw the structure for these isomer: \[\ce{[Pt(NH3)(H2O)Cl2]}\]
