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प्रश्न
Draw all the isomers (geometrical and optical) of [CoCl2(en)2]+.
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उत्तर
trans [CoCl2(en)2]+
cis [CoCl2(en)2]+ optical isomers (d and l)
संबंधित प्रश्न
Explain cationic complexes and anionic complexes of co-ordination compounds.
Draw one of the geometrical isomers of the complex [Pt(en)2Cl2]2+ which is optically active.
Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:
K[Cr(H2O)2(C2O4)2]
How many geometrical isomers are possible in the following coordination entity?
[Cr(C2O4)3]3−
Draw the structure of optical isomers of [PtCl2(en)2]2+.
Draw all the isomers (geometrical and optical) of [Co(NH3)Cl(en)2]2+.
Draw all the isomers (geometrical and optical) of [Co(NH3)2Cl2(en)]+.
Write the structures of optical isomers of the complex ion [Co(en)2Cl2]+.
What type of structural isomers are [Co(NH3)5 Br] SO4 and [Co(NH3)5 SO4]Br? Give a chemical test to distinguish the isomers.
Answer the following question.
Write IUPAC name of the complex [Pt(en)2CI2]. Draw structures of geometrical isomers for this complex.
Identify the optically active compounds from the following:
(i) \[\ce{[Co(en)3]^{3+}}\]
(ii) \[\ce{[trans - [Co(en)2Cl2]^+}\]
(iii) \[\ce{cis - [Co(en)2Cl2]^+}\]
(iv) \[\ce{[Cr(NH3)5Cl]}\]
Which one of the following complexes shows optical isomerism? (en = ethylenediamine)
Which of the following molecules has a chiral centre correctly labelled with an asterisk (*)?
Assertion (A): Trans [CrCl2(ox)2]3− shows optical isomerism.
Reason (R): Optical isomerism is common in octahedral complexes involving didentate ligands.
Indicate the types of isomerism exhibited by the following complex and draw the structure for these isomer: \[\ce{[Pt(NH3)(H2O)Cl2]}\]
