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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

How many geometrical isomers are possible in the following coordination entity? [Cr(C2O4)3]3−

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प्रश्न

How many geometrical isomers are possible in the following coordination entity? 

[Cr(C2O4)3]3−

अति संक्षिप्त उत्तर
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उत्तर

It is a complex [Cr(C2O4)3]3− of the type [M(AA)3]± and is unable to show geometrical isomerism. Hence, no geometric isomer is possible as it is a bidentate ligand.

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Isomerism in Coordination Compounds - Stereoisomerism
  या प्रश्नात किंवा उत्तरात काही त्रुटी आहे का?
पाठ 5: Coordinate Compounds - Exercises [पृष्ठ १३८]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
पाठ 5 Coordinate Compounds
Exercises | Q 5.9 (i) | पृष्ठ १३८
नूतन Chemistry [English] Class 12 ISC
पाठ 5 Coordination Compounds
'NCERT TEXT-BOOK' Exercises | Q 9.9 (i) | पृष्ठ ५५८

संबंधित प्रश्‍न

What type of isomerism is exhibited by the complex [Co(en)3]3+?

(en = ethane-1,2-diamine)


Define the following term:

Anomers 


Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer: 

K[Cr(H2O)2(C2O4)2]


Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:

[Pt(NH3)(H2O)Cl2]


Draw all the isomers (geometrical and optical) of [Co(NH3)2Cl2(en)]+.


Write all the geometrical isomers of [Pt(NH3)(Br)(Cl)(py)] and how many of these will exhibit optical isomers?


What type of isomers are `[Co(NH_3)_5Br]SO_4`and `[Co(NH_3)_5SO_4]Br`?. Give a  chemical test to distinguish between them.


Write the structures of optical isomers of the complex ion [Co(en)2Cl2]+.


Draw the geometrical isomers of complex [Pt(en)2Cl2]2+.


Name the type of isomerism exhibited by the following pairs of compound:
(1) (C2H5)2NH and CH3-NH-C3H7
(2) 1 – butanol and 2 methyl-1 -propanol.


Name the type of isomerism shown by the following pair of compounds:

[CoCl(H2O)(NH3)4]Cl2 and [CoCl2(NH3)4]Cl.H2O


Answer the following question.
Write IUPAC name of the complex [Pt(en)2CI2]. Draw structures of geometrical isomers for this complex.


Name the type of isomerism shown by the following pair of compounds:

[Cr(NH3)5Br]SO4 and [Cr(NH3)5SO4]Br


Indicate the type of isomerism exhibited by the following complex and draw the structure for this isomer: \[\ce{[Pt(NH3)(H2O)Cl2]}\]


Indicate the types of isomerism exhibited by the following complex and draw the structure for these isomer: \[\ce{[Pt(NH3)(H2O)Cl2]}\]


Indicate the types of isomerism exhibited by the following complex and draw the structure for this isomer:

\[\ce{[Pt(NH3)(H2O)Cl2]}\]


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