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प्रश्न
Draw the geometrical isomers of [Co(en)2Cl2]2+. Which geometrical isomer of [Co(en)2Cl2]2+ is not optically active and why?
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उत्तर
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| cis-form | trans-form |
The trans isomer of [Co(en)2Cl2]2+ is not optically active because of the plane of symmetry.
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संबंधित प्रश्न
Explain cationic complexes and anionic complexes of co-ordination compounds.
Draw the geometrical isomers of complex \[\ce{[Co(en)2Cl2]+}\].
Draw one of the geometrical isomers of the complex [Pt(en)2Cl2]2+ which is optically active.
How many geometrical isomers are possible in the following coordination entity?
[Co(NH3)3Cl3]
Draw the structure of optical isomers of [PtCl2(en)2]2+.
Why is Butan-1-ol optically inactive but Butan-2-ol is optically active?
Identify the optically active compounds from the following:
(i) \[\ce{[Co(en)3]^{3+}}\]
(ii) \[\ce{[trans - [Co(en)2Cl2]^+}\]
(iii) \[\ce{cis - [Co(en)2Cl2]^+}\]
(iv) \[\ce{[Cr(NH3)5Cl]}\]
Name the type of isomerism shown by the following pair of compounds:
[Cr(NH3)5Br]SO4 and [Cr(NH3)5SO4]Br
Which one of the following complexes shows optical isomerism? (en = ethylenediamine)
Indicate the types of isomerism exhibited by the following complex and draw the structure for this isomer:
\[\ce{[Pt(NH3)(H2O)Cl2]}\]
