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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Draw all the isomers (geometrical and optical) of [Co(NH3)Cl(en)2]2+.

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प्रश्न

Draw all the isomers (geometrical and optical) of [Co(NH3)Cl(en)2]2+.

Write the structures of all the possible stereoisomers of the complex [CoCl(en)2(NH3)]2+.

रासायनिक समीकरणे/रचना
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उत्तर


        trans-isomer


       cis-isomer optical isomerism

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Isomerism in Coordination Compounds - Stereoisomerism
  या प्रश्नात किंवा उत्तरात काही त्रुटी आहे का?
पाठ 5: Coordinate Compounds - Exercises [पृष्ठ १३९]

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संबंधित प्रश्‍न

Explain cationic complexes and anionic complexes of co-ordination compounds.


Draw one of the geometrical isomers of the complex [Pt(en)2Cl2]2+ which is optically active.


Draw the geometrical isomers of complex [Pt(NH3)2Cl2].


Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:

[Co(en)3]Cl3


Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:

[Co(NH3)5(NO2)](NO3)2


Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:

[Pt(NH3)(H2O)Cl2]


How many geometrical isomers are possible in the following coordination entity? 

[Cr(C2O4)3]3−


Draw the structure of optical isomers of [PtCl2(en)2]2+.


Write the structures of optical isomers of the complex ion [Co(en)2Cl2]+.


Why is Butan-1-ol optically inactive but Butan-2-ol is optically active?


What type of structural isomers are [Co(NH3)5 Br] SO4 and [Co(NH3)5 SO4]Br? Give a chemical test to distinguish the isomers. 


Write the IUPAC name of [Co(en)2Cl2]+ ion.


Identify the optically active compounds from the following:

(i) \[\ce{[Co(en)3]^{3+}}\]

(ii) \[\ce{[trans - [Co(en)2Cl2]^+}\]

(iii) \[\ce{cis - [Co(en)2Cl2]^+}\]

(iv) \[\ce{[Cr(NH3)5Cl]}\]


The complex [(Pt(Py)(NH3)BrCl] will have how many geometrical isomers?


Draw the geometrical isomers of [Co(en)2Cl2]2+. Which geometrical isomer of [Co(en)2Cl2]2+ is not optically active and why?


Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers: [Pt(NH3)(H2O)Cl2]


Indicate the types of isomerism exhibited by the following complex and draw the structure for this isomer:

\[\ce{[Pt(NH3)(H2O)Cl2]}\]


Indicate the types of isomerism exhibited by the following complex and draw the structure for this isomer:

\[\ce{[Pt(NH3)(H2O)Cl2]}\]


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