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प्रश्न
Assertion (A): Trans [CrCl2(ox)2]3− shows optical isomerism.
Reason (R): Optical isomerism is common in octahedral complexes involving didentate ligands.
पर्याय
Both Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of the Assertion (A).
Both Assertion (A) and Reason (R) are true, but Reason (R) is not the correct explanation of the Assertion (A).
Assertion (A) is true, but Reason (R) is false.
Assertion (A) is false, but Reason (R) is true.
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उत्तर
Assertion (A) is false, but Reason (R) is true.
Explanation:
Optical isomers are mirror images that cannot be superimposed on each other, hence, cis[CrCl2(OX)2]3− is chiral, and trans[CrCl2(OX)2]3− is symmetrical and not optically active.
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संबंधित प्रश्न
When a coordination compound CoCl3.6NH3 is mixed with AgNO3, 3 moles of AgCl are precipitated per mole of the compound. Write the structural formula of the coordination compound.
Draw the geometrical isomers of complex [Pt(NH3)2Cl2].
Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:
[Co(NH3)5(NO2)](NO3)2
Draw the structure of optical isomers of [Cr(NH3)2Cl2(en)]+.
Draw all the isomers (geometrical and optical) of [CoCl2(en)2]+.
Name the type of isomerism that the compound with molecular formula C3H6O2 exhibits. Represent the isomers.
Name the type of isomerism shown by the following pair of compounds:
[CoCl(H2O)(NH3)4]Cl2 and [CoCl2(NH3)4]Cl.H2O
Answer the following question.
Write IUPAC name of the complex [Pt(en)2CI2]. Draw structures of geometrical isomers for this complex.
Identify the optically active compounds from the following:
(i) \[\ce{[Co(en)3]^{3+}}\]
(ii) \[\ce{[trans - [Co(en)2Cl2]^+}\]
(iii) \[\ce{cis - [Co(en)2Cl2]^+}\]
(iv) \[\ce{[Cr(NH3)5Cl]}\]
Which of the following molecules has a chiral centre correctly labelled with an asterisk (*)?
