Advertisements
Advertisements
प्रश्न
Assertion (A): Trans [CrCl2(ox)2]3− shows optical isomerism.
Reason (R): Optical isomerism is common in octahedral complexes involving didentate ligands.
विकल्प
Both Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of the Assertion (A).
Both Assertion (A) and Reason (R) are true, but Reason (R) is not the correct explanation of the Assertion (A).
Assertion (A) is true, but Reason (R) is false.
Assertion (A) is false, but Reason (R) is true.
Advertisements
उत्तर
Assertion (A) is false, but Reason (R) is true.
Explanation:
Optical isomers are mirror images that cannot be superimposed on each other, hence, cis[CrCl2(OX)2]3− is chiral, and trans[CrCl2(OX)2]3− is symmetrical and not optically active.

APPEARS IN
संबंधित प्रश्न
Draw the geometrical isomers of complex \[\ce{[Co(en)2Cl2]+}\].
What type of isomerism is exhibited by the complex [Co(en)3]3+?
(en = ethane-1,2-diamine)
Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:
[Co(NH3)5(NO2)](NO3)2
Draw the structure of optical isomers of [Cr(C2O4)3]3−.
Draw the structure of optical isomers of [Cr(NH3)2Cl2(en)]+.
Write all the geometrical isomers of [Pt(NH3)(Br)(Cl)(py)] and how many of these will exhibit optical isomers?
Write the structures of optical isomers of the complex ion [Co(en)2Cl2]+.
Answer the following question.
Write IUPAC name of the complex [Pt(en)2CI2]. Draw structures of geometrical isomers for this complex.
Which one of the following complexes shows optical isomerism? (en = ethylenediamine)
Indicate the types of isomerism exhibited by the following complex and draw the structure for these isomer: \[\ce{[Pt(NH3)(H2O)Cl2]}\]
