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प्रश्न
Draw all the isomers (geometrical and optical) of [Co(NH3)2Cl2(en)]+.
Draw all the isomers (geometrical and optical) of [CoCl2(en)(NH3)2]+.
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उत्तर
(i)
(ii)
(iii)
(iv)
All are asymmetric. Hence, all will show optical isomerism, i.e. d(+) and l(−) forms, which are non-superimposable mirror images.
संबंधित प्रश्न
Draw one of the geometrical isomers of the complex [Pt(en)2Cl2]2+ which is optically active.
Define the following term:
Anomers
Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:
[Co(en)3]Cl3
Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:
[Co(NH3)5(NO2)](NO3)2
Draw the structure of optical isomers of [Cr(NH3)2Cl2(en)]+.
Write all the geometrical isomers of [Pt(NH3)(Br)(Cl)(py)] and how many of these will exhibit optical isomers?
Write the structures of optical isomers of the complex ion [Co(en)2Cl2]+.
Draw the geometrical isomers of complex [Pt(en)2Cl2]2+.
What type of structural isomers are [Co(NH3)5 Br] SO4 and [Co(NH3)5 SO4]Br? Give a chemical test to distinguish the isomers.
The IUPAC name for [CoCl(NO2)(en)2]Cl is ____________.
Identify the optically active compounds from the following:
(i) \[\ce{[Co(en)3]^{3+}}\]
(ii) \[\ce{[trans - [Co(en)2Cl2]^+}\]
(iii) \[\ce{cis - [Co(en)2Cl2]^+}\]
(iv) \[\ce{[Cr(NH3)5Cl]}\]
Name the type of isomerism shown by the following pair of compounds:
[Cr(NH3)5Br]SO4 and [Cr(NH3)5SO4]Br
Which one of the following complexes shows optical isomerism? (en = ethylenediamine)
Draw the geometrical isomers of [Co(en)2Cl2]2+. Which geometrical isomer of [Co(en)2Cl2]2+ is not optically active and why?
Indicate the types of isomerism exhibited by the following complexes and draw the structure for isomers:
\[\ce{[Pt(NH3)(H2O)Cl2]}\]
Assertion: Addition of bromine water to 1-butene gives two optical isomers.
Reason: The product formed contains two asymmetric carbon atoms.
Indicate the type of isomerism exhibited by the following complex and draw the structure for this isomer:
[Pt(NH3)(H2O)Cl2]
Indicate the types of isomerism exhibited by the following complex and draw the structure for this isomer:
\[\ce{[Pt(NH3)(H2O)Cl2]}\]
Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:
\[\ce{[Pt(NH3 )(H2O)Cl2]}\]
