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How many geometrical isomers are possible in the following coordination entity? [Co(NH3)3Cl3] - Chemistry

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प्रश्न

How many geometrical isomers are possible in the following coordination entity? 

[Co(NH3)3Cl3]

How many geometrical isomers are possible in the following coordination entity? 

[CoCl3(NH3)3]

अति संक्षिप्त उत्तर
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उत्तर

Two (fac- and mer-) geometrical isomers are possible.

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Isomerism in Coordination Compounds - Stereoisomerism
  या प्रश्नात किंवा उत्तरात काही त्रुटी आहे का?
पाठ 5: Coordinate Compounds - Exercises [पृष्ठ १३८]

APPEARS IN

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संबंधित प्रश्‍न

Draw the geometrical isomers of complex [Pt(NH3)2Cl2].


What type of isomerism is exhibited by the complex [Co(en)3]3+?

(en = ethane-1,2-diamine)


Indicate the types of isomerism exhibited by the following complex and draw the structures for these isomers:

K[Cr(H2O)2(C2O4)2]


Indicate the types of isomerism exhibited by the following complex and draw the structures for these isomers:

[Co(NH3)5(NO2)](NO3)2


How many geometrical isomers are possible in the following coordination entity? 

[Cr(C2O4)3]3−


Draw the structure of optical isomers of [Cr(NH3)2Cl2(en)]+.


Write all the geometrical isomers of [Pt(NH3)(Br)(Cl)(py)] and how many of these will exhibit optical isomers?


Name the type of isomerism that the compound with molecular formula C3H6O2 exhibits. Represent the isomers.


Answer the following question.
Write IUPAC name of the complex [Pt(en)2CI2]. Draw structures of geometrical isomers for this complex.


Identify the optically active compounds from the following:

(i) \[\ce{[Co(en)3]^{3+}}\]

(ii) \[\ce{[trans - [Co(en)2Cl2]^+}\]

(iii) \[\ce{cis - [Co(en)2Cl2]^+}\]

(iv) \[\ce{[Cr(NH3)5Cl]}\]


Name the type of isomerism shown by the following pair of compounds:

[Cr(NH3)5Br]SO4 and [Cr(NH3)5SO4]Br


Draw the geometrical isomers of [Co(en)2Cl2]2+. Which geometrical isomer of [Co(en)2Cl2]2+ is not optically active and why?


Which of the following molecules has a chiral centre correctly labelled with an asterisk (*)?


Assertion (A): Trans [CrCl2(ox)2]3− shows optical isomerism.

Reason (R): Optical isomerism is common in octahedral complexes involving didentate ligands.


Indicate the types of isomerism exhibited by the following complexes and draw the structure for isomers:

\[\ce{[Pt(NH3)(H2O)Cl2]}\]


Indicate the types of isomerism exhibited by the following complex and draw the structure for this isomer:

\[\ce{[Pt(NH3)(H2O)Cl2]}\]


Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:

\[\ce{[Pt(NH3 )(H2O)Cl2]}\]


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