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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

How many geometrical isomers are possible in the following coordination entity? [Co(NH3)3Cl3]

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प्रश्न

How many geometrical isomers are possible in the following coordination entity? 

[Co(NH3)3Cl3]

How many geometrical isomers are possible in the following coordination entity? 

[CoCl3(NH3)3]

अति संक्षिप्त उत्तर
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उत्तर

Two (facial and meridional) geometrical isomers are possible.

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Isomerism in Coordination Compounds - Stereoisomerism
  या प्रश्नात किंवा उत्तरात काही त्रुटी आहे का?
पाठ 5: Coordinate Compounds - Exercises [पृष्ठ १३८]

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संबंधित प्रश्‍न

Draw one of the geometrical isomers of the complex [Pt (en)2Cl2] +2 which is optically inactive


Draw the geometrical isomers of complex [Pt(NH3)2Cl2].


What type of isomerism is exhibited by the complex [Co(en)3]3+?

(en = ethane-1,2-diamine)


Define the following term:

Anomers 


Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:

[Pt(NH3)(H2O)Cl2]


Draw the structure of optical isomers of [PtCl2(en)2]2+.


Draw the structure of optical isomers of [Cr(NH3)2Cl2(en)]+.


Draw all the isomers (geometrical and optical) of [Co(NH3)Cl(en)2]2+.


Write the structures of optical isomers of the complex ion [Co(en)2Cl2]+.


Why is Butan-1-ol optically inactive but Butan-2-ol is optically active?


What type of structural isomers are [Co(NH3)5 Br] SO4 and [Co(NH3)5 SO4]Br? Give a chemical test to distinguish the isomers. 


Name the type of isomerism exhibited by the following pairs of compound:
(1) (C2H5)2NH and CH3-NH-C3H7
(2) 1 – butanol and 2 methyl-1 -propanol.


Write the IUPAC name of [Co(en)2Cl2]+ ion.


Identify the optically active compounds from the following:

(i) \[\ce{[Co(en)3]^{3+}}\]

(ii) \[\ce{[trans - [Co(en)2Cl2]^+}\]

(iii) \[\ce{cis - [Co(en)2Cl2]^+}\]

(iv) \[\ce{[Cr(NH3)5Cl]}\]


Assertion (A): Trans [CrCl2(ox)2]3− shows optical isomerism.

Reason (R): Optical isomerism is common in octahedral complexes involving didentate ligands.


Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers: 

[Pt(NH3)(H2O)Cl2 ]


Indicate the type of isomerism exhibited by the following complex and draw the structure for this isomer: \[\ce{[Pt(NH3)(H2O)Cl2]}\]


Indicate the types of isomerism exhibited by the following complexes and draw the structure for these isomer:

\[\ce{[Pt(NH3)(H2O)Cl2]}\]


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