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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Draw the structure of optical isomers of [PtCl2(en)2]2+. - Chemistry

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प्रश्न

Draw the structure of optical isomers of [PtCl2(en)2]2+.

रासायनिक समीकरणे/रचना
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उत्तर

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Isomerism in Coordination Compounds - Stereoisomerism
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पाठ 5: Coordinate Compounds - Exercises [पृष्ठ १३८]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
पाठ 5 Coordinate Compounds
Exercises | Q 5.10 (ii) | पृष्ठ १३८

संबंधित प्रश्‍न

Explain cationic complexes and anionic complexes of co-ordination compounds.


When a coordination compound CoCl3.6NH3 is mixed with AgNO3, 3 moles of AgCl are precipitated per mole of the compound. Write the structural formula of the coordination compound.


Draw one of the geometrical isomers of the complex [Pt (en)2Cl2] +2 which is optically inactive


Draw one of the geometrical isomers of the complex [Pt(en)2Cl2]2+ which is optically active.


Indicate the types of isomerism exhibited by the following complex and draw the structures for these isomers:

K[Cr(H2O)2(C2O4)2]


Indicate the types of isomerism exhibited by the following complex and draw the structures for these isomers:

[Co(NH3)5(NO2)](NO3)2


Draw all the isomers (geometrical and optical) of [Co(NH3)Cl(en)2]2+.


Name the type of isomerism exhibited by the following pairs of compound:
(1) (C2H5)2NH and CH3-NH-C3H7
(2) 1 – butanol and 2 methyl-1 -propanol.


Identify the optically active compounds from the following:

(i) \[\ce{[Co(en)3]^{3+}}\]

(ii) \[\ce{[trans - [Co(en)2Cl2]^+}\]

(iii) \[\ce{cis - [Co(en)2Cl2]^+}\]

(iv) \[\ce{[Cr(NH3)5Cl]}\]


Name the type of isomerism shown by the following pair of compounds:

[Cr(NH3)5Br]SO4 and [Cr(NH3)5SO4]Br


Assertion (A): Trans [CrCl2(ox)2]3− shows optical isomerism.

Reason (R): Optical isomerism is common in octahedral complexes involving didentate ligands.


Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers: [Pt(NH3)(H2O)Cl2]


Assertion: Addition of bromine water to 1-butene gives two optical isomers.

Reason: The product formed contains two asymmetric carbon atoms.


Indicate the type of isomerism exhibited by the following complex and draw the structure for this isomer: \[\ce{[Pt(NH3)(H2O)Cl2]}\]


Indicate the types of isomerism exhibited by the following complex and draw the structure for this isomer:

\[\ce{[Pt(NH3)(H2O)Cl2]}\]


Indicate the types of isomerism exhibited by the following complex and draw the structure for this isomer:

\[\ce{[Pt(NH3)(H2O)Cl2]}\]


Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:

\[\ce{[Pt(NH3 )(H2O)Cl2]}\]


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