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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer: [Co(NH3)5(NO2)](NO3)2

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प्रश्न

Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:

[Co(NH3)5(NO2)](NO3)2

रासायनिक समीकरणे/रचना
लघु उत्तर
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उत्तर

There are 10 possible isomers. (Geometrical, ionisation and linkage isomers)

It can also show linkage isomerism.

[Co(NH3)5(NO2)](NO3)and [Co(NH3)5(ONO)](NO3)2

It can also show ionization isomerism.

[Co(NH3)5(NO2)](NO3)2 and [CO(NH3)5(NO3)](NO3)(NO2)

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Isomerism in Coordination Compounds - Stereoisomerism
  या प्रश्नात किंवा उत्तरात काही त्रुटी आहे का?
पाठ 5: Coordinate Compounds - Intext Questions [पृष्ठ १२८]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
पाठ 5 Coordinate Compounds
Intext Questions | Q 5.3 (iii) | पृष्ठ १२८

संबंधित प्रश्‍न

Explain cationic complexes and anionic complexes of co-ordination compounds.


Define the following term:

Anomers 


Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:

[Pt(NH3)(H2O)Cl2]


How many geometrical isomers are possible in the following coordination entity? 

[Co(NH3)3Cl3]


Draw all the isomers (geometrical and optical) of [CoCl2(en)2]+.


Write all the geometrical isomers of [Pt(NH3)(Br)(Cl)(py)] and how many of these will exhibit optical isomers?


What type of isomers are `[Co(NH_3)_5Br]SO_4`and `[Co(NH_3)_5SO_4]Br`?. Give a  chemical test to distinguish between them.


Write the structures of optical isomers of the complex ion [Co(en)2Cl2]+.


Name the type of isomerism shown by the following pair of compounds:

[CoCl(H2O)(NH3)4]Cl2 and [CoCl2(NH3)4]Cl.H2O


Identify the optically active compounds from the following:

(i) \[\ce{[Co(en)3]^{3+}}\]

(ii) \[\ce{[trans - [Co(en)2Cl2]^+}\]

(iii) \[\ce{cis - [Co(en)2Cl2]^+}\]

(iv) \[\ce{[Cr(NH3)5Cl]}\]


The complex [(Pt(Py)(NH3)BrCl] will have how many geometrical isomers?


Draw the geometrical isomers of [Co(en)2Cl2]2+. Which geometrical isomer of [Co(en)2Cl2]2+ is not optically active and why?


Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers: 

[Pt(NH3)(H2O)Cl2 ]


Indicate the types of isomerism exhibited by the following complexes and draw the structure for isomers:

\[\ce{[Pt(NH3)(H2O)Cl2]}\]


Assertion: Addition of bromine water to 1-butene gives two optical isomers.

Reason: The product formed contains two asymmetric carbon atoms.


Indicate the type of isomerism exhibited by the following complex and draw the structure for this isomer: \[\ce{[Pt(NH3)(H2O)Cl2]}\]


Indicate the types of isomerism exhibited by the following complexes and draw the structure for these isomer:

\[\ce{[Pt(NH3)(H2O)Cl2]}\]


Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:

\[\ce{[Pt(NH3 )(H2O)Cl2]}\]


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