मराठी
कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer: [Co(en)3]Cl3

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प्रश्न

Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:

[Co(en)3]Cl3

रासायनिक समीकरणे/रचना
अति संक्षिप्त उत्तर
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उत्तर १

Two optical isomers for [Co(en)3]Cl3 exits.

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उत्तर २

It may have two optical isomers.

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Isomerism in Coordination Compounds - Stereoisomerism
  या प्रश्नात किंवा उत्तरात काही त्रुटी आहे का?
पाठ 5: Coordinate Compounds - Intext Questions [पृष्ठ १२८]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
पाठ 5 Coordinate Compounds
Intext Questions | Q 5.3 (ii) | पृष्ठ १२८

संबंधित प्रश्‍न

Explain cationic complexes and anionic complexes of co-ordination compounds.


When a coordination compound CoCl3.6NH3 is mixed with AgNO3, 3 moles of AgCl are precipitated per mole of the compound. Write the structural formula of the coordination compound.


Define the following term:

Anomers 


Draw all the isomers (geometrical and optical) of [Co(NH3)Cl(en)2]2+.


Write all the geometrical isomers of [Pt(NH3)(Br)(Cl)(py)] and how many of these will exhibit optical isomers?


What type of isomers are `[Co(NH_3)_5Br]SO_4`and `[Co(NH_3)_5SO_4]Br`?. Give a  chemical test to distinguish between them.


Why is Butan-1-ol optically inactive but Butan-2-ol is optically active?


What type of structural isomers are [Co(NH3)5 Br] SO4 and [Co(NH3)5 SO4]Br? Give a chemical test to distinguish the isomers. 


Name the type of isomerism that the compound with molecular formula C3H6O2 exhibits. Represent the isomers.


Write the IUPAC name of [Co(en)2Cl2]+ ion.


Identify the optically active compounds from the following:

(i) \[\ce{[Co(en)3]^{3+}}\]

(ii) \[\ce{[trans - [Co(en)2Cl2]^+}\]

(iii) \[\ce{cis - [Co(en)2Cl2]^+}\]

(iv) \[\ce{[Cr(NH3)5Cl]}\]


The complex [(Pt(Py)(NH3)BrCl] will have how many geometrical isomers?


Which one of the following complexes shows optical isomerism? (en = ethylenediamine)


Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers: 

[Pt(NH3)(H2O)Cl2 ]


Assertion: Addition of bromine water to 1-butene gives two optical isomers.

Reason: The product formed contains two asymmetric carbon atoms.


Indicate the type of isomerism exhibited by the following complex and draw the structure for this isomer: \[\ce{[Pt(NH3)(H2O)Cl2]}\]


Indicate the types of isomerism exhibited by the following complex and draw the structure for this isomer:

\[\ce{[Pt(NH3)(H2O)Cl2]}\]


Indicate the types of isomerism exhibited by the following complex and draw the structure for this isomer:

\[\ce{[Pt(NH3)(H2O)Cl2]}\]


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