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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer: [Co(en)3]Cl3

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प्रश्न

Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:

[Co(en)3]Cl3

रासायनिक समीकरणे/रचना
अति संक्षिप्त उत्तर
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उत्तर १

Two optical isomers for [Co(en)3]Cl3 exits.

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उत्तर २

It may have two optical isomers.

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Isomerism in Coordination Compounds - Stereoisomerism
  या प्रश्नात किंवा उत्तरात काही त्रुटी आहे का?
पाठ 5: Coordinate Compounds - Intext Questions [पृष्ठ १२८]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
पाठ 5 Coordinate Compounds
Intext Questions | Q 5.3 (ii) | पृष्ठ १२८

संबंधित प्रश्‍न

When a coordination compound CoCl3.6NH3 is mixed with AgNO3, 3 moles of AgCl are precipitated per mole of the compound. Write the structural formula of the coordination compound.


Draw the geometrical isomers of complex \[\ce{[Co(en)2Cl2]+}\].


Define the following term:

Anomers 


Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:

[Co(NH3)5(NO2)](NO3)2


How many geometrical isomers are possible in the following coordination entity? 

[Cr(C2O4)3]3−


How many geometrical isomers are possible in the following coordination entity? 

[Co(NH3)3Cl3]


Draw the structure of optical isomers of [Cr(C2O4)3]3−.


Draw the structure of optical isomers of [PtCl2(en)2]2+.


Draw the structure of optical isomers of [Cr(NH3)2Cl2(en)]+.


Draw all the isomers (geometrical and optical) of [Co(NH3)2Cl2(en)]+.


Write all the geometrical isomers of [Pt(NH3)(Br)(Cl)(py)] and how many of these will exhibit optical isomers?


Name the type of isomerism shown by the following pair of compounds:

[CoCl(H2O)(NH3)4]Cl2 and [CoCl2(NH3)4]Cl.H2O


Answer the following question.
Write IUPAC name of the complex [Pt(en)2CI2]. Draw structures of geometrical isomers for this complex.


Identify the optically active compounds from the following:

(i) \[\ce{[Co(en)3]^{3+}}\]

(ii) \[\ce{[trans - [Co(en)2Cl2]^+}\]

(iii) \[\ce{cis - [Co(en)2Cl2]^+}\]

(iv) \[\ce{[Cr(NH3)5Cl]}\]


Which of the following molecules has a chiral centre correctly labelled with an asterisk (*)?


Indicate the types of isomerism exhibited by the following complexes and draw the structure for isomers:

\[\ce{[Pt(NH3)(H2O)Cl2]}\]


Indicate the types of isomerism exhibited by the following complex and draw the structure for this isomer:

\[\ce{[Pt(NH3)(H2O)Cl2]}\]


Indicate the types of isomerism exhibited by the following complex and draw the structure for this isomer:

\[\ce{[Pt(NH3)(H2O)Cl2]}\]


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