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Karnataka Board PUCPUC Science 2nd PUC Class 12

Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer: [Co(NH3)5(NO2)](NO3)2

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Question

Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:

[Co(NH3)5(NO2)](NO3)2

Chemical Equations/Structures
Short Answer
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Solution

There are 10 possible isomers. (Geometrical, ionisation and linkage isomers)

It can also show linkage isomerism.

[Co(NH3)5(NO2)](NO3)and [Co(NH3)5(ONO)](NO3)2

It can also show ionization isomerism.

[Co(NH3)5(NO2)](NO3)2 and [CO(NH3)5(NO3)](NO3)(NO2)

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Isomerism in Coordination Compounds - Stereoisomerism
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Chapter 5: Coordinate Compounds - Intext Questions [Page 128]

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NCERT Chemistry Part 1 and 2 [English] Class 12
Chapter 5 Coordinate Compounds
Intext Questions | Q 5.3 (iii) | Page 128

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