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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer: [Co(NH3)5(NO2)](NO3)2

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प्रश्न

Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:

[Co(NH3)5(NO2)](NO3)2

रासायनिक समीकरण/संरचनाएँ
लघु उत्तरीय
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उत्तर

There are 10 possible isomers. (Geometrical, ionisation and linkage isomers)

It can also show linkage isomerism.

[Co(NH3)5(NO2)](NO3)and [Co(NH3)5(ONO)](NO3)2

It can also show ionization isomerism.

[Co(NH3)5(NO2)](NO3)2 and [CO(NH3)5(NO3)](NO3)(NO2)

shaalaa.com
Isomerism in Coordination Compounds - Stereoisomerism
  क्या इस प्रश्न या उत्तर में कोई त्रुटि है?
अध्याय 5: Coordinate Compounds - Intext Questions [पृष्ठ १२८]

APPEARS IN

एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
अध्याय 5 Coordinate Compounds
Intext Questions | Q 5.3 (iii) | पृष्ठ १२८

संबंधित प्रश्न

Explain cationic complexes and anionic complexes of co-ordination compounds.


Draw the geometrical isomers of complex \[\ce{[Co(en)2Cl2]+}\].


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Draw the geometrical isomers of complex [Pt(NH3)2Cl2].


How many geometrical isomers are possible in the following coordination entity? 

[Cr(C2O4)3]3−


Draw the structure of optical isomers of [Cr(C2O4)3]3−.


Draw all the isomers (geometrical and optical) of [Co(NH3)Cl(en)2]2+.


Draw all the isomers (geometrical and optical) of [Co(NH3)2Cl2(en)]+.


Name the type of isomerism that the compound with molecular formula C3H6O2 exhibits. Represent the isomers.


Answer the following question.
Write IUPAC name of the complex [Pt(en)2CI2]. Draw structures of geometrical isomers for this complex.


The IUPAC name for [CoCl(NO2)(en)2]Cl is ____________.


Identify the optically active compounds from the following:

(i) \[\ce{[Co(en)3]^{3+}}\]

(ii) \[\ce{[trans - [Co(en)2Cl2]^+}\]

(iii) \[\ce{cis - [Co(en)2Cl2]^+}\]

(iv) \[\ce{[Cr(NH3)5Cl]}\]


Draw the geometrical isomers of [Co(en)2Cl2]2+. Which geometrical isomer of [Co(en)2Cl2]2+ is not optically active and why?


Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers: 

[Pt(NH3)(H2O)Cl2 ]


Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers: [Pt(NH3)(H2O)Cl2]


Indicate the type of isomerism exhibited by the following complex and draw the structure for this isomer: \[\ce{[Pt(NH3)(H2O)Cl2]}\]


Indicate the types of isomerism exhibited by the following complex and draw the structure for this isomer:

\[\ce{[Pt(NH3)(H2O)Cl2]}\]


Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:

\[\ce{[Pt(NH3 )(H2O)Cl2]}\]


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