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प्रश्न
Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:
[Co(NH3)5(NO2)](NO3)2
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उत्तर
There are 10 possible isomers. (Geometrical, ionisation and linkage isomers)
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It can also show linkage isomerism.
[Co(NH3)5(NO2)](NO3)2 and [Co(NH3)5(ONO)](NO3)2
It can also show ionization isomerism.
[Co(NH3)5(NO2)](NO3)2 and [CO(NH3)5(NO3)](NO3)(NO2)
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संबंधित प्रश्न
Explain cationic complexes and anionic complexes of co-ordination compounds.
Draw one of the geometrical isomers of the complex [Pt(en)2Cl2]2+ which is optically active.
Define the following term:
Anomers
Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:
[Pt(NH3)(H2O)Cl2]
How many geometrical isomers are possible in the following coordination entity?
[Co(NH3)3Cl3]
Draw all the isomers (geometrical and optical) of [CoCl2(en)2]+.
Write all the geometrical isomers of [Pt(NH3)(Br)(Cl)(py)] and how many of these will exhibit optical isomers?
Draw the geometrical isomers of complex [Pt(en)2Cl2]2+.
Name the type of isomerism exhibited by the following pairs of compound:
(1) (C2H5)2NH and CH3-NH-C3H7
(2) 1 – butanol and 2 methyl-1 -propanol.
Answer the following question.
Write IUPAC name of the complex [Pt(en)2CI2]. Draw structures of geometrical isomers for this complex.
The IUPAC name for [CoCl(NO2)(en)2]Cl is ____________.
Identify the optically active compounds from the following:
(i) \[\ce{[Co(en)3]^{3+}}\]
(ii) \[\ce{[trans - [Co(en)2Cl2]^+}\]
(iii) \[\ce{cis - [Co(en)2Cl2]^+}\]
(iv) \[\ce{[Cr(NH3)5Cl]}\]
Draw the geometrical isomers of [Co(en)2Cl2]2+. Which geometrical isomer of [Co(en)2Cl2]2+ is not optically active and why?
Which of the following molecules has a chiral centre correctly labelled with an asterisk (*)?
Assertion (A): Trans [CrCl2(ox)2]3− shows optical isomerism.
Reason (R): Optical isomerism is common in octahedral complexes involving didentate ligands.
Indicate the types of isomerism exhibited by the following complexes and draw the structure for these isomer:
\[\ce{[Pt(NH3)(H2O)Cl2]}\]
