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प्रश्न
Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:
[Co(NH3)5(NO2)](NO3)2
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उत्तर
There are 10 possible isomers. (Geometrical, ionisation and linkage isomers)
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It can also show linkage isomerism.
[Co(NH3)5(NO2)](NO3)2 and [Co(NH3)5(ONO)](NO3)2
It can also show ionization isomerism.
[Co(NH3)5(NO2)](NO3)2 and [CO(NH3)5(NO3)](NO3)(NO2)
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संबंधित प्रश्न
Draw the geometrical isomers of complex \[\ce{[Co(en)2Cl2]+}\].
Draw one of the geometrical isomers of the complex [Pt(en)2Cl2]2+ which is optically active.
Define the following term:
Anomers
Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:
[Pt(NH3)(H2O)Cl2]
Draw the structure of optical isomers of [Cr(NH3)2Cl2(en)]+.
Draw all the isomers (geometrical and optical) of [CoCl2(en)2]+.
Draw all the isomers (geometrical and optical) of [Co(NH3)Cl(en)2]2+.
Draw all the isomers (geometrical and optical) of [Co(NH3)2Cl2(en)]+.
Draw the geometrical isomers of complex [Pt(en)2Cl2]2+.
Name the type of isomerism shown by the following pair of compounds:
[CoCl(H2O)(NH3)4]Cl2 and [CoCl2(NH3)4]Cl.H2O
Write the IUPAC name of [Co(en)2Cl2]+ ion.
The IUPAC name for [CoCl(NO2)(en)2]Cl is ____________.
Identify the optically active compounds from the following:
(i) \[\ce{[Co(en)3]^{3+}}\]
(ii) \[\ce{[trans - [Co(en)2Cl2]^+}\]
(iii) \[\ce{cis - [Co(en)2Cl2]^+}\]
(iv) \[\ce{[Cr(NH3)5Cl]}\]
Assertion (A): Trans [CrCl2(ox)2]3− shows optical isomerism.
Reason (R): Optical isomerism is common in octahedral complexes involving didentate ligands.
Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers: [Pt(NH3)(H2O)Cl2]
Indicate the type of isomerism exhibited by the following complex and draw the structure for this isomer:
[Pt(NH3)(H2O)Cl2]
Indicate the types of isomerism exhibited by the following complexes and draw the structure for these isomer:
\[\ce{[Pt(NH3)(H2O)Cl2]}\]
Indicate the types of isomerism exhibited by the following complex and draw the structure for this isomer:
\[\ce{[Pt(NH3)(H2O)Cl2]}\]
