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Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer: [Pt(NH3)(H2O)Cl2]

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प्रश्न

Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:

[Pt(NH3)(H2O)Cl2]

रासायनिक समीकरण/संरचनाएँ
लघु उत्तरीय
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उत्तर

Geometrical (cis, trans) isomers of [Pt(NH3)(H2O)Cl2] can exist.

\[\begin{array}{cc}
\phantom{..}\ce{Cl}\phantom{.....}\ce{NH3}\\
\backslash\phantom{...}/\\
\ce{Pt}\\
/\phantom{...}\backslash\\
\ce{\underset{Cis}{\phantom{..}Cl\phantom{.....}H2O}}
\end{array}\]

\[\begin{array}{cc}
\ce{H3N}\phantom{.....}\ce{Cl}\phantom{..}\\
\backslash\phantom{...}/\\
\ce{Pt}\\
/\phantom{...}\backslash\\
\ce{\underset{Trans}{\phantom{..}Cl\phantom{.....}H2O}}
\end{array}\]

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Isomerism in Coordination Compounds - Stereoisomerism
  क्या इस प्रश्न या उत्तर में कोई त्रुटि है?
अध्याय 5: Coordinate Compounds - Intext Questions [पृष्ठ १२८]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
अध्याय 5 Coordinate Compounds
Intext Questions | Q 5.3 (iv) | पृष्ठ १२८

संबंधित प्रश्न

Explain cationic complexes and anionic complexes of co-ordination compounds.


Draw one of the geometrical isomers of the complex [Pt(en)2Cl2]2+ which is optically active.


Define the following term:

Anomers 


Draw all the isomers (geometrical and optical) of [CoCl2(en)2]+.


What type of isomers are `[Co(NH_3)_5Br]SO_4`and `[Co(NH_3)_5SO_4]Br`?. Give a  chemical test to distinguish between them.


Why is Butan-1-ol optically inactive but Butan-2-ol is optically active?


Draw the geometrical isomers of complex [Pt(en)2Cl2]2+.


What type of structural isomers are [Co(NH3)5 Br] SO4 and [Co(NH3)5 SO4]Br? Give a chemical test to distinguish the isomers. 


Name the type of isomerism exhibited by the following pairs of compound:
(1) (C2H5)2NH and CH3-NH-C3H7
(2) 1 – butanol and 2 methyl-1 -propanol.


Name the type of isomerism shown by the following pair of compounds:

[CoCl(H2O)(NH3)4]Cl2 and [CoCl2(NH3)4]Cl.H2O


Identify the optically active compounds from the following:

(i) \[\ce{[Co(en)3]^{3+}}\]

(ii) \[\ce{[trans - [Co(en)2Cl2]^+}\]

(iii) \[\ce{cis - [Co(en)2Cl2]^+}\]

(iv) \[\ce{[Cr(NH3)5Cl]}\]


Draw the geometrical isomers of [Co(en)2Cl2]2+. Which geometrical isomer of [Co(en)2Cl2]2+ is not optically active and why?


Which of the following molecules has a chiral centre correctly labelled with an asterisk (*)?


Assertion (A): Trans [CrCl2(ox)2]3− shows optical isomerism.

Reason (R): Optical isomerism is common in octahedral complexes involving didentate ligands.


Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers: 

[Pt(NH3)(H2O)Cl2 ]


Indicate the types of isomerism exhibited by the following complexes and draw the structure for isomers:

\[\ce{[Pt(NH3)(H2O)Cl2]}\]


Indicate the type of isomerism exhibited by the following complex and draw the structure for this isomer: \[\ce{[Pt(NH3)(H2O)Cl2]}\]


Indicate the types of isomerism exhibited by the following complex and draw the structure for these isomer: \[\ce{[Pt(NH3)(H2O)Cl2]}\]


Indicate the types of isomerism exhibited by the following complex and draw the structure for this isomer:

\[\ce{[Pt(NH3)(H2O)Cl2]}\]


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