Advertisements
Advertisements
प्रश्न
Identify the optically active compounds from the following:
(i) \[\ce{[Co(en)3]^{3+}}\]
(ii) \[\ce{[trans - [Co(en)2Cl2]^+}\]
(iii) \[\ce{cis - [Co(en)2Cl2]^+}\]
(iv) \[\ce{[Cr(NH3)5Cl]}\]
Advertisements
उत्तर
(i) \[\ce{[Co(en)3]^{3+}}\]
(iii) \[\ce{cis - [Co(en)2Cl2]^+}\]
Explanation:
\[\ce{[Co(en)3]^{3+}}\] and \[\ce{[Co(en)2Cl2]^{2+}}\] are optically active compounds because their mirror images are non-superimposable isomer.

Non – superimposable isomers of \[\ce{[Co(en)3]^{3+}}\]

Non – superimosable isomers of \[\ce{[Co(en)2Cl2]^+}\]
APPEARS IN
संबंधित प्रश्न
Explain cationic complexes and anionic complexes of co-ordination compounds.
When a coordination compound CoCl3.6NH3 is mixed with AgNO3, 3 moles of AgCl are precipitated per mole of the compound. Write the structural formula of the coordination compound.
Draw one of the geometrical isomers of the complex [Pt(en)2Cl2]2+ which is optically active.
What type of isomerism is exhibited by the complex [Co(en)3]3+?
(en = ethane-1,2-diamine)
Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:
K[Cr(H2O)2(C2O4)2]
Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:
[Co(en)3]Cl3
Draw the structure of optical isomers of [Cr(NH3)2Cl2(en)]+.
Draw all the isomers (geometrical and optical) of [Co(NH3)Cl(en)2]2+.
Why is Butan-1-ol optically inactive but Butan-2-ol is optically active?
Draw the geometrical isomers of complex [Pt(en)2Cl2]2+.
Name the type of isomerism that the compound with molecular formula C3H6O2 exhibits. Represent the isomers.
Which one of the following complexes shows optical isomerism? (en = ethylenediamine)
Which of the following molecules has a chiral centre correctly labelled with an asterisk (*)?
Assertion (A): Trans [CrCl2(ox)2]3− shows optical isomerism.
Reason (R): Optical isomerism is common in octahedral complexes involving didentate ligands.
Indicate the type of isomerism exhibited by the following complex and draw the structure for this isomer: \[\ce{[Pt(NH3)(H2O)Cl2]}\]
Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:
\[\ce{[Pt(NH3 )(H2O)Cl2]}\]
