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प्रश्न
Identify the optically active compounds from the following:
(i) \[\ce{[Co(en)3]^{3+}}\]
(ii) \[\ce{[trans - [Co(en)2Cl2]^+}\]
(iii) \[\ce{cis - [Co(en)2Cl2]^+}\]
(iv) \[\ce{[Cr(NH3)5Cl]}\]
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उत्तर
(i) \[\ce{[Co(en)3]^{3+}}\]
(iii) \[\ce{cis - [Co(en)2Cl2]^+}\]
Explanation:
\[\ce{[Co(en)3]^{3+}}\] and \[\ce{[Co(en)2Cl2]^{2+}}\] are optically active compounds because their mirror images are non-superimposable isomer.
Non – superimposable isomers of \[\ce{[Co(en)3]^{3+}}\]
Non – superimosable isomers of \[\ce{[Co(en)2Cl2]^+}\]
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संबंधित प्रश्न
Draw one of the geometrical isomers of the complex [Pt (en)2Cl2] +2 which is optically inactive
What type of isomerism is exhibited by the complex [Co(en)3]3+?
(en = ethane-1,2-diamine)
Define the following term:
Anomers
Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:
[Co(en)3]Cl3
Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:
[Pt(NH3)(H2O)Cl2]
How many geometrical isomers are possible in the following coordination entity?
[Cr(C2O4)3]3−
Draw all the isomers (geometrical and optical) of [Co(NH3)Cl(en)2]2+.
Draw all the isomers (geometrical and optical) of [Co(NH3)2Cl2(en)]+.
What type of isomers are `[Co(NH_3)_5Br]SO_4`and `[Co(NH_3)_5SO_4]Br`?. Give a chemical test to distinguish between them.
Draw the geometrical isomers of complex [Pt(en)2Cl2]2+.
The IUPAC name for [CoCl(NO2)(en)2]Cl is ____________.
The complex [(Pt(Py)(NH3)BrCl] will have how many geometrical isomers?
Which one of the following complexes shows optical isomerism? (en = ethylenediamine)
Which of the following molecules has a chiral centre correctly labelled with an asterisk (*)?
Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers:
[Pt(NH3)(H2O)Cl2 ]
Assertion: Addition of bromine water to 1-butene gives two optical isomers.
Reason: The product formed contains two asymmetric carbon atoms.
Indicate the type of isomerism exhibited by the following complex and draw the structure for this isomer: \[\ce{[Pt(NH3)(H2O)Cl2]}\]
Indicate the types of isomerism exhibited by the following complex and draw the structure for this isomer:
\[\ce{[Pt(NH3)(H2O)Cl2]}\]
