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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Identify the optically active compounds from the following: (i) [Co(en)X3]X3+ (ii) [trans−[Co(en)X2ClX2]X+ (iii) cis−[Co(en)X2ClX2]X+ (iv) [Cr(NHX3)X5Cl]

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प्रश्न

Identify the optically active compounds from the following:

(i) \[\ce{[Co(en)3]^{3+}}\]

(ii) \[\ce{[trans - [Co(en)2Cl2]^+}\]

(iii) \[\ce{cis - [Co(en)2Cl2]^+}\]

(iv) \[\ce{[Cr(NH3)5Cl]}\]

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उत्तर

(i) \[\ce{[Co(en)3]^{3+}}\]

(iii) \[\ce{cis - [Co(en)2Cl2]^+}\]

Explanation:

\[\ce{[Co(en)3]^{3+}}\] and \[\ce{[Co(en)2Cl2]^{2+}}\] are optically active compounds because their mirror images are non-superimposable isomer.


Non – superimposable isomers of \[\ce{[Co(en)3]^{3+}}\]


Non – superimosable isomers of \[\ce{[Co(en)2Cl2]^+}\]

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Isomerism in Coordination Compounds - Stereoisomerism
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अध्याय 9: Coordination Compounds - Exercises [पृष्ठ १२३]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
अध्याय 9 Coordination Compounds
Exercises | Q II. 21. | पृष्ठ १२३

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