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प्रश्न
Draw all the isomers (geometrical and optical) of [Co(NH3)2Cl2(en)]+.
Draw all the isomers (geometrical and optical) of [CoCl2(en)(NH3)2]+.
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उत्तर
(i)
(ii)
(iii)
(iv)
All are asymmetric. Hence, all will show optical isomerism, i.e. d(+) and l(-) forms, which are non-superimposable mirror images.
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संबंधित प्रश्न
Draw one of the geometrical isomers of the complex [Pt (en)2Cl2] +2 which is optically inactive
Draw one of the geometrical isomers of the complex [Pt(en)2Cl2]2+ which is optically active.
Draw the geometrical isomers of complex [Pt(NH3)2Cl2].
Indicate the types of isomerism exhibited by the following complex and draw the structures for these isomers:
K[Cr(H2O)2(C2O4)2]
Draw the structure of optical isomers of [Cr(C2O4)3]3−.
Draw the structure of optical isomers of [PtCl2(en)2]2+.
Draw the structure of optical isomers of [Cr(NH3)2Cl2(en)]+.
Draw all the isomers (geometrical and optical) of [CoCl2(en)2]+.
Draw all the isomers (geometrical and optical) of [Co(NH3)Cl(en)2]2+.
What type of isomers are `[Co(NH_3)_5Br]SO_4`and `[Co(NH_3)_5SO_4]Br`?. Give a chemical test to distinguish between them.
What type of structural isomers are [Co(NH3)5 Br] SO4 and [Co(NH3)5 SO4]Br? Give a chemical test to distinguish the isomers.
Answer the following question.
Write IUPAC name of the complex [Pt(en)2CI2]. Draw structures of geometrical isomers for this complex.
Name the type of isomerism shown by the following pair of compounds:
[Cr(NH3)5Br]SO4 and [Cr(NH3)5SO4]Br
Draw the geometrical isomers of [Co(en)2Cl2]2+. Which geometrical isomer of [Co(en)2Cl2]2+ is not optically active and why?
Which of the following molecules has a chiral centre correctly labelled with an asterisk (*)?
Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers:
[Pt(NH3)(H2O)Cl2 ]
Indicate the types of isomerism exhibited by the following complexes and draw the structure for isomers:
\[\ce{[Pt(NH3)(H2O)Cl2]}\]
Indicate the types of isomerism exhibited by the following complexes and draw the structure for these isomer:
\[\ce{[Pt(NH3)(H2O)Cl2]}\]
Indicate the types of isomerism exhibited by the following complex and draw the structure for this isomer:
\[\ce{[Pt(NH3)(H2O)Cl2]}\]
