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प्रश्न
Draw all the isomers (geometrical and optical) of [Co(NH3)2Cl2(en)]+.
Draw all the isomers (geometrical and optical) of [CoCl2(en)(NH3)2]+.
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उत्तर
(i)
(ii)
(iii)
(iv)
All are asymmetric. Hence, all will show optical isomerism, i.e. d(+) and l(-) forms, which are non-superimposable mirror images.
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संबंधित प्रश्न
When a coordination compound CoCl3.6NH3 is mixed with AgNO3, 3 moles of AgCl are precipitated per mole of the compound. Write the structural formula of the coordination compound.
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Draw the geometrical isomers of complex [Pt(NH3)2Cl2].
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Indicate the types of isomerism exhibited by the following complex and draw the structures for these isomers:
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Indicate the types of isomerism exhibited by the following complex and draw the structures for these isomers:
[Co(NH3)5(NO2)](NO3)2
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Name the type of isomerism exhibited by the following pairs of compound:
(1) (C2H5)2NH and CH3-NH-C3H7
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Name the type of isomerism shown by the following pair of compounds:
[CoCl(H2O)(NH3)4]Cl2 and [CoCl2(NH3)4]Cl.H2O
Write the IUPAC name of [Co(en)2Cl2]+ ion.
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(i) \[\ce{[Co(en)3]^{3+}}\]
(ii) \[\ce{[trans - [Co(en)2Cl2]^+}\]
(iii) \[\ce{cis - [Co(en)2Cl2]^+}\]
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Assertion: Addition of bromine water to 1-butene gives two optical isomers.
Reason: The product formed contains two asymmetric carbon atoms.
Indicate the type of isomerism exhibited by the following complex and draw the structure for this isomer:
[Pt(NH3)(H2O)Cl2]
Indicate the type of isomerism exhibited by the following complex and draw the structure for this isomer: \[\ce{[Pt(NH3)(H2O)Cl2]}\]
Indicate the types of isomerism exhibited by the following complex and draw the structure for this isomer:
\[\ce{[Pt(NH3)(H2O)Cl2]}\]
Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:
\[\ce{[Pt(NH3 )(H2O)Cl2]}\]
