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प्रश्न
Draw all the isomers (geometrical and optical) of [Co(NH3)2Cl2(en)]+.
Draw all the isomers (geometrical and optical) of [CoCl2(en)(NH3)2]+.
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उत्तर
(i)
(ii)
(iii)
(iv)
All are asymmetric. Hence, all will show optical isomerism, i.e. d(+) and l(−) forms, which are non-superimposable mirror images.
संबंधित प्रश्न
Draw one of the geometrical isomers of the complex [Pt(en)2Cl2]2+ which is optically active.
How many geometrical isomers are possible in the following coordination entity?
[Cr(C2O4)3]3−
How many geometrical isomers are possible in the following coordination entity?
[Co(NH3)3Cl3]
Draw the structure of optical isomers of [PtCl2(en)2]2+.
Draw the structure of optical isomers of [Cr(NH3)2Cl2(en)]+.
Draw all the isomers (geometrical and optical) of [Co(NH3)Cl(en)2]2+.
What type of isomers are `[Co(NH_3)_5Br]SO_4`and `[Co(NH_3)_5SO_4]Br`?. Give a chemical test to distinguish between them.
Draw the geometrical isomers of complex [Pt(en)2Cl2]2+.
Name the type of isomerism shown by the following pair of compounds:
[CoCl(H2O)(NH3)4]Cl2 and [CoCl2(NH3)4]Cl.H2O
Write the IUPAC name of [Co(en)2Cl2]+ ion.
Name the type of isomerism shown by the following pair of compounds:
[Cr(NH3)5Br]SO4 and [Cr(NH3)5SO4]Br
The complex [(Pt(Py)(NH3)BrCl] will have how many geometrical isomers?
Which one of the following complexes shows optical isomerism? (en = ethylenediamine)
Draw the geometrical isomers of [Co(en)2Cl2]2+. Which geometrical isomer of [Co(en)2Cl2]2+ is not optically active and why?
Assertion (A): Trans [CrCl2(ox)2]3− shows optical isomerism.
Reason (R): Optical isomerism is common in octahedral complexes involving didentate ligands.
Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers:
[Pt(NH3)(H2O)Cl2 ]
Assertion: Addition of bromine water to 1-butene gives two optical isomers.
Reason: The product formed contains two asymmetric carbon atoms.
Indicate the type of isomerism exhibited by the following complex and draw the structure for this isomer: \[\ce{[Pt(NH3)(H2O)Cl2]}\]
Indicate the types of isomerism exhibited by the following complex and draw the structure for this isomer:
\[\ce{[Pt(NH3)(H2O)Cl2]}\]
