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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Draw all the isomers (geometrical and optical) of [Co(NH3)2Cl2(en)]+.

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प्रश्न

Draw all the isomers (geometrical and optical) of [Co(NH3)2Cl2(en)]+.

Draw all the isomers (geometrical and optical) of [CoCl2(en)(NH3)2]+.

रासायनिक समीकरण/संरचनाएँ
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उत्तर

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Isomerism in Coordination Compounds - Stereoisomerism
  क्या इस प्रश्न या उत्तर में कोई त्रुटि है?
अध्याय 5: Coordinate Compounds - Exercises [पृष्ठ १३९]

APPEARS IN

एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
अध्याय 5 Coordinate Compounds
Exercises | Q 5.11 (iii) | पृष्ठ १३९
नूतन Chemistry [English] Class 12 ISC
अध्याय 5 Coordination Compounds
SHORT ANSWER TYPE QUESTIONS | Q 45. (c) | पृष्ठ ५४७
नूतन Chemistry [English] Class 12 ISC
अध्याय 5 Coordination Compounds
'NCERT TEXT-BOOK' Exercises | Q 9.11 (iii) | पृष्ठ ५५८

संबंधित प्रश्न

Draw one of the geometrical isomers of the complex [Pt (en)2Cl2] +2 which is optically inactive


Draw the geometrical isomers of complex \[\ce{[Co(en)2Cl2]+}\].


Define the following term:

Anomers 


How many geometrical isomers are possible in the following coordination entity? 

[Cr(C2O4)3]3−


Draw the structure of optical isomers of [Cr(C2O4)3]3−.


Draw all the isomers (geometrical and optical) of [Co(NH3)Cl(en)2]2+.


Write all the geometrical isomers of [Pt(NH3)(Br)(Cl)(py)] and how many of these will exhibit optical isomers?


Why is Butan-1-ol optically inactive but Butan-2-ol is optically active?


What type of structural isomers are [Co(NH3)5 Br] SO4 and [Co(NH3)5 SO4]Br? Give a chemical test to distinguish the isomers. 


Name the type of isomerism shown by the following pair of compounds:

[CoCl(H2O)(NH3)4]Cl2 and [CoCl2(NH3)4]Cl.H2O


Write the IUPAC name of [Co(en)2Cl2]+ ion.


Answer the following question.
Write IUPAC name of the complex [Pt(en)2CI2]. Draw structures of geometrical isomers for this complex.


Identify the optically active compounds from the following:

(i) \[\ce{[Co(en)3]^{3+}}\]

(ii) \[\ce{[trans - [Co(en)2Cl2]^+}\]

(iii) \[\ce{cis - [Co(en)2Cl2]^+}\]

(iv) \[\ce{[Cr(NH3)5Cl]}\]


Which one of the following complexes shows optical isomerism? (en = ethylenediamine)


Assertion (A): Trans [CrCl2(ox)2]3− shows optical isomerism.

Reason (R): Optical isomerism is common in octahedral complexes involving didentate ligands.


Indicate the type of isomerism exhibited by the following complex and draw the structure for this isomer: \[\ce{[Pt(NH3)(H2O)Cl2]}\]


Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:

\[\ce{[Pt(NH3 )(H2O)Cl2]}\]


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