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प्रश्न
Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:
[Co(NH3)5(NO2)](NO3)2
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उत्तर
There are 10 possible isomers. (Geometrical, ionisation and linkage isomers)
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It can also show linkage isomerism.
[Co(NH3)5(NO2)](NO3)2 and [Co(NH3)5(ONO)](NO3)2
It can also show ionization isomerism.
[Co(NH3)5(NO2)](NO3)2 and [CO(NH3)5(NO3)](NO3)(NO2)
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संबंधित प्रश्न
Explain cationic complexes and anionic complexes of co-ordination compounds.
Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:
[Pt(NH3)(H2O)Cl2]
Draw the structure of optical isomers of [PtCl2(en)2]2+.
Draw all the isomers (geometrical and optical) of [CoCl2(en)2]+.
Draw all the isomers (geometrical and optical) of [Co(NH3)2Cl2(en)]+.
Write all the geometrical isomers of [Pt(NH3)(Br)(Cl)(py)] and how many of these will exhibit optical isomers?
What type of isomers are `[Co(NH_3)_5Br]SO_4`and `[Co(NH_3)_5SO_4]Br`?. Give a chemical test to distinguish between them.
Draw the geometrical isomers of complex [Pt(en)2Cl2]2+.
Name the type of isomerism exhibited by the following pairs of compound:
(1) (C2H5)2NH and CH3-NH-C3H7
(2) 1 – butanol and 2 methyl-1 -propanol.
Name the type of isomerism that the compound with molecular formula C3H6O2 exhibits. Represent the isomers.
The IUPAC name for [CoCl(NO2)(en)2]Cl is ____________.
Identify the optically active compounds from the following:
(i) \[\ce{[Co(en)3]^{3+}}\]
(ii) \[\ce{[trans - [Co(en)2Cl2]^+}\]
(iii) \[\ce{cis - [Co(en)2Cl2]^+}\]
(iv) \[\ce{[Cr(NH3)5Cl]}\]
The complex [(Pt(Py)(NH3)BrCl] will have how many geometrical isomers?
Assertion (A): Trans [CrCl2(ox)2]3− shows optical isomerism.
Reason (R): Optical isomerism is common in octahedral complexes involving didentate ligands.
Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers:
[Pt(NH3)(H2O)Cl2 ]
Indicate the types of isomerism exhibited by the following complexes and draw the structure for isomers:
\[\ce{[Pt(NH3)(H2O)Cl2]}\]
Assertion: Addition of bromine water to 1-butene gives two optical isomers.
Reason: The product formed contains two asymmetric carbon atoms.
