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प्रश्न
Write all the geometrical isomers of [Pt(NH3)(Br)(Cl)(py)] and how many of these will exhibit optical isomers?
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उत्तर
| \[\begin{array}{cc} \ce{NH3}\phantom{.....}\ce{Br}\\ \phantom{.}\backslash\phantom{...}/\\ \ce{Pt}\\ /\phantom{...}\backslash\\ \ce{Cl}\phantom{.....}\ce{Py}\phantom{.} \end{array}\] |
\[\begin{array}{cc} \ce{H3N}\phantom{.....}\ce{Br}\phantom{.}\\ \phantom{.}\backslash\phantom{...}/\\ \ce{Pt}\\ /\phantom{...}\backslash\\ \ce{Py}\phantom{.....}\ce{Cl}\ \end{array}\] |
\[\begin{array}{cc} \ce{H3N}\phantom{.....}\ce{Cl}\phantom{.}\\ \phantom{.}\backslash\phantom{...}/\\ \ce{Pt}\\ /\phantom{...}\backslash\\ \ce{Py}\phantom{.....}\ce{Br}\ \end{array}\] |
Square planar complexes never show optical isomerism because of the plane of symmetry present in this case.
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संबंधित प्रश्न
Draw the geometrical isomers of complex \[\ce{[Co(en)2Cl2]+}\].
Draw the geometrical isomers of complex [Pt(NH3)2Cl2].
Define the following term:
Anomers
Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:
K[Cr(H2O)2(C2O4)2]
Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:
[Co(NH3)5(NO2)](NO3)2
How many geometrical isomers are possible in the following coordination entity?
[Cr(C2O4)3]3−
How many geometrical isomers are possible in the following coordination entity?
[Co(NH3)3Cl3]
Draw the structure of optical isomers of [Cr(NH3)2Cl2(en)]+.
Draw all the isomers (geometrical and optical) of [CoCl2(en)2]+.
Write the structures of optical isomers of the complex ion [Co(en)2Cl2]+.
Name the type of isomerism shown by the following pair of compounds:
[CoCl(H2O)(NH3)4]Cl2 and [CoCl2(NH3)4]Cl.H2O
Identify the optically active compounds from the following:
(i) \[\ce{[Co(en)3]^{3+}}\]
(ii) \[\ce{[trans - [Co(en)2Cl2]^+}\]
(iii) \[\ce{cis - [Co(en)2Cl2]^+}\]
(iv) \[\ce{[Cr(NH3)5Cl]}\]
Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers: [Pt(NH3)(H2O)Cl2]
Assertion: Addition of bromine water to 1-butene gives two optical isomers.
Reason: The product formed contains two asymmetric carbon atoms.
Indicate the types of isomerism exhibited by the following complex and draw the structure for these isomer: \[\ce{[Pt(NH3)(H2O)Cl2]}\]
Indicate the types of isomerism exhibited by the following complexes and draw the structure for these isomer:
\[\ce{[Pt(NH3)(H2O)Cl2]}\]
Indicate the types of isomerism exhibited by the following complex and draw the structure for this isomer:
\[\ce{[Pt(NH3)(H2O)Cl2]}\]
Indicate the types of isomerism exhibited by the following complex and draw the structure for this isomer:
\[\ce{[Pt(NH3)(H2O)Cl2]}\]
