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प्रश्न
Identify the optically active compounds from the following:
(i) \[\ce{[Co(en)3]^{3+}}\]
(ii) \[\ce{[trans - [Co(en)2Cl2]^+}\]
(iii) \[\ce{cis - [Co(en)2Cl2]^+}\]
(iv) \[\ce{[Cr(NH3)5Cl]}\]
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उत्तर
(i) \[\ce{[Co(en)3]^{3+}}\]
(iii) \[\ce{cis - [Co(en)2Cl2]^+}\]
Explanation:
\[\ce{[Co(en)3]^{3+}}\] and \[\ce{[Co(en)2Cl2]^{2+}}\] are optically active compounds because their mirror images are non-superimposable isomer.
Non – superimposable isomers of \[\ce{[Co(en)3]^{3+}}\]
Non – superimosable isomers of \[\ce{[Co(en)2Cl2]^+}\]
APPEARS IN
संबंधित प्रश्न
Draw the geometrical isomers of complex \[\ce{[Co(en)2Cl2]+}\].
Define the following term:
Anomers
Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:
[Co(NH3)5(NO2)](NO3)2
How many geometrical isomers are possible in the following coordination entity?
[Cr(C2O4)3]3−
How many geometrical isomers are possible in the following coordination entity?
[Co(NH3)3Cl3]
Draw the structure of optical isomers of [Cr(C2O4)3]3−.
Draw all the isomers (geometrical and optical) of [CoCl2(en)2]+.
Draw all the isomers (geometrical and optical) of [Co(NH3)2Cl2(en)]+.
Write the structures of optical isomers of the complex ion [Co(en)2Cl2]+.
Why is Butan-1-ol optically inactive but Butan-2-ol is optically active?
Draw the geometrical isomers of complex [Pt(en)2Cl2]2+.
Name the type of isomerism exhibited by the following pairs of compound:
(1) (C2H5)2NH and CH3-NH-C3H7
(2) 1 – butanol and 2 methyl-1 -propanol.
Write the IUPAC name of [Co(en)2Cl2]+ ion.
Draw the geometrical isomers of [Co(en)2Cl2]2+. Which geometrical isomer of [Co(en)2Cl2]2+ is not optically active and why?
Assertion (A): Trans [CrCl2(ox)2]3− shows optical isomerism.
Reason (R): Optical isomerism is common in octahedral complexes involving didentate ligands.
Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers:
[Pt(NH3)(H2O)Cl2 ]
Indicate the types of isomerism exhibited by the following complexes and draw the structure for isomers:
\[\ce{[Pt(NH3)(H2O)Cl2]}\]
Indicate the types of isomerism exhibited by the following complexes and draw the structure for these isomer:
\[\ce{[Pt(NH3)(H2O)Cl2]}\]
