Advertisements
Advertisements
प्रश्न
Identify the optically active compounds from the following:
(i) \[\ce{[Co(en)3]^{3+}}\]
(ii) \[\ce{[trans - [Co(en)2Cl2]^+}\]
(iii) \[\ce{cis - [Co(en)2Cl2]^+}\]
(iv) \[\ce{[Cr(NH3)5Cl]}\]
Advertisements
उत्तर
(i) \[\ce{[Co(en)3]^{3+}}\]
(iii) \[\ce{cis - [Co(en)2Cl2]^+}\]
Explanation:
\[\ce{[Co(en)3]^{3+}}\] and \[\ce{[Co(en)2Cl2]^{2+}}\] are optically active compounds because their mirror images are non-superimposable isomer.
Non – superimposable isomers of \[\ce{[Co(en)3]^{3+}}\]
Non – superimosable isomers of \[\ce{[Co(en)2Cl2]^+}\]
APPEARS IN
संबंधित प्रश्न
Draw one of the geometrical isomers of the complex [Pt(en)2Cl2]2+ which is optically active.
Draw the geometrical isomers of complex [Pt(NH3)2Cl2].
What type of isomerism is exhibited by the complex [Co(en)3]3+?
(en = ethane-1,2-diamine)
Define the following term:
Anomers
Indicate the types of isomerism exhibited by the following complex and draw the structures for these isomers:
K[Cr(H2O)2(C2O4)2]
How many geometrical isomers are possible in the following coordination entity?
[Co(NH3)3Cl3]
Draw the structure of optical isomers of [PtCl2(en)2]2+.
Draw all the isomers (geometrical and optical) of [Co(NH3)2Cl2(en)]+.
Write all the geometrical isomers of [Pt(NH3)(Br)(Cl)(py)] and how many of these will exhibit optical isomers?
Name the type of isomerism exhibited by the following pairs of compound:
(1) (C2H5)2NH and CH3-NH-C3H7
(2) 1 – butanol and 2 methyl-1 -propanol.
Name the type of isomerism that the compound with molecular formula C3H6O2 exhibits. Represent the isomers.
Name the type of isomerism shown by the following pair of compounds:
[CoCl(H2O)(NH3)4]Cl2 and [CoCl2(NH3)4]Cl.H2O
Draw the geometrical isomers of [Co(en)2Cl2]2+. Which geometrical isomer of [Co(en)2Cl2]2+ is not optically active and why?
Which of the following molecules has a chiral centre correctly labelled with an asterisk (*)?
Assertion (A): Trans [CrCl2(ox)2]3− shows optical isomerism.
Reason (R): Optical isomerism is common in octahedral complexes involving didentate ligands.
Indicate the types of isomerism exhibited by the following complexes and draw the structure for isomers:
\[\ce{[Pt(NH3)(H2O)Cl2]}\]
Indicate the type of isomerism exhibited by the following complex and draw the structure for this isomer: \[\ce{[Pt(NH3)(H2O)Cl2]}\]
Indicate the types of isomerism exhibited by the following complexes and draw the structure for these isomer:
\[\ce{[Pt(NH3)(H2O)Cl2]}\]
Indicate the types of isomerism exhibited by the following complex and draw the structure for this isomer:
\[\ce{[Pt(NH3)(H2O)Cl2]}\]
Indicate the type of isomerism exhibited by the following complex and draw the structure for the isomer:
\[\ce{[Pt(NH3 )(H2O)Cl2]}\]
