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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Indicate the types of isomerism exhibited by the following complex and draw the structures for these isomers: K[Cr(H2O)2(C2O4)2] - Chemistry

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प्रश्न

Indicate the types of isomerism exhibited by the following complex and draw the structures for these isomers:

K[Cr(H2O)2(C2O4)2]

रासायनिक समीकरणे/रचना
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उत्तर

Both geometrical (cis-, trans-) and optical isomers for cis are possible.

(a) Geometrical isomers (cis-trans):

(b) Optical isomers of cis (d- and l-):

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Isomerism in Coordination Compounds - Stereoisomerism
  या प्रश्नात किंवा उत्तरात काही त्रुटी आहे का?
पाठ 5: Coordinate Compounds - Intext Questions [पृष्ठ १२८]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
पाठ 5 Coordinate Compounds
Intext Questions | Q 5.3 (i) | पृष्ठ १२८

संबंधित प्रश्‍न

Define the following term:

Anomers 


Indicate the types of isomerism exhibited by the following complex and draw the structures for these isomers:

[Co(en)3]Cl3


Indicate the types of isomerism exhibited by the following complex and draw the structures for these isomers:

[Co(NH3)5(NO2)](NO3)2


Indicate the types of isomerism exhibited by the following complex and draw the structure for this isomer:

[Pt(NH3)(H2O)Cl2]


How many geometrical isomers are possible in the following coordination entity? 

[Cr(C2O4)3]3−


How many geometrical isomers are possible in the following coordination entity? 

[Co(NH3)3Cl3]


Draw the structure of optical isomers of [Cr(C2O4)3]3−.


Draw all the isomers (geometrical and optical) of [Co(NH3)Cl(en)2]2+.


Write all the geometrical isomers of [Pt(NH3)(Br)(Cl)(py)] and how many of these will exhibit optical isomers?


Write the structures of optical isomers of the complex ion [Co(en)2Cl2]+.


Name the type of isomerism that the compound with molecular formula C3H6O2 exhibits. Represent the isomers.


Name the type of isomerism shown by the following pair of compounds:

[CoCl(H2O)(NH3)4]Cl2 and [CoCl2(NH3)4]Cl.H2O


Answer the following question.
Write IUPAC name of the complex [Pt(en)2CI2]. Draw structures of geometrical isomers for this complex.


Name the type of isomerism shown by the following pair of compounds:

[Cr(NH3)5Br]SO4 and [Cr(NH3)5SO4]Br


The complex [(Pt(Py)(NH3)BrCl] will have how many geometrical isomers?


Draw the geometrical isomers of [Co(en)2Cl2]2+. Which geometrical isomer of [Co(en)2Cl2]2+ is not optically active and why?


Indicate the type of isomerism exhibited by the following complex and draw the structure for this isomer: \[\ce{[Pt(NH3)(H2O)Cl2]}\]


Indicate the types of isomerism exhibited by the following complex and draw the structure for these isomer: \[\ce{[Pt(NH3)(H2O)Cl2]}\]


Indicate the types of isomerism exhibited by the following complexes and draw the structure for these isomer:

\[\ce{[Pt(NH3)(H2O)Cl2]}\]


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