Advertisements
Advertisements
प्रश्न
Using the concept of quantum numbers, calculate the maximum numbers of electrons present in the ‘M’ shell. Give their distribution in shells, subshells, and orbitals.
Advertisements
उत्तर
- Each main shell contains a maximum of 2n2 electrons.
For ‘M’ shell, n = 3.
Therefore, the maximum numbers of electrons present in the ‘M’ shell = 2 × (3)2 = 18. - The distribution of these electrons in shells, subshells, and orbitals can be given as follows:
Value of n Values of l Values of ml Values of ms 3 0 0 `±1/2` 1 −1 `±1/2` 0 `±1/2` +1 `±1/2` 2 −2 `±1/2` −1 `±1/2` 0 `±1/2` +1 `±1/2` +2 `±1/2`
APPEARS IN
संबंधित प्रश्न
Using s, p, d notations, describe the orbital with the following quantum numbers n = 4; l =3.
State Heisenberg uncertainty principle.
Give the names of quantum numbers.
Define the term Electronic configuration.
State and explain Pauli’s exclusion principle.
State Hund’s rule of maximum multiplicity with a suitable example.
State the order of filling atomic orbitals following Aufbau principle.
Write condensed orbital notation of electronic configuration of the following element:
Carbon (Z = 6)
Explain in brief, the significance of the azimuthal quantum number.
If n = 3, what are the quantum number l and m?
The principal quantum number (n) and magnetic quantum number (ml) for the valence electrons of rubidium atom (Z = 37) are ____________ respectively.
The designation of a subshell with n = 6 and l = 2 is ____________.
The three electrons have the following set of quantum numbers:
X = 6, 1, −1, `+1/2`
Y = 6, 0, 0, `+1/2`
Z = 5, 1, 0, `+1/2`
Identify the CORRECT statement.
Which of the following has a greater number of electrons than neutrons?
(Mass number of Mg, C, O and Na is 24, 12, 16 and 23 respectively).
Which of the following properties of atom could be explained correctly by Thomson Model of atom?
The number of radial nodes for 3p orbital is ______.
Total number of orbitals associated with third shell will be ______.
Nickel atom can lose two electrons to form \[\ce{Ni^{2+}}\] ion. The atomic number of nickel is 28. From which orbital will nickel lose two electrons.
Which of the following orbitals are degenerate?
3dxy, 4dxy 3dz2, 3dyz, 4dyz, 4dz2
Calculate the total number of angular nodes and radial nodes present in 3p orbital.
The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.
Based upon the above information, arrange the following orbitals in the increasing order of energy.
5f, 6d, 7s, 7p
The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.
Based upon the above information, solve the questions given below:
Which of the following orbitals has the lowest energy?
4d, 4f, 5s, 5p
The electronic configuration of valence shell of Cu is 3d104s1 and not 3d94s2. How is this configuration explained?
Match the following species with their corresponding ground state electronic configuration.
| Atom / Ion | Electronic configuration |
| (i) \[\ce{Cu}\] | (a) 1s2 2s2 2p6 3s2 3p6 3d10 |
| (ii) \[\ce{Cu^{2+}}\] | (b) 1s2 2s2 2p6 3s2 3p6 3d10 4s2 |
| (iii) \[\ce{Zn^{2+}}\] | (c) 1s2 2s2 2p6 3s2 3p6 3d10 4s1 |
| (iv) \[\ce{Cr^{3+}}\] | (d) 1s2 2s2 2p6 3s2 3p6 3d9 |
| (e) 1s2 2s2 2p6 3s2 3p6 3d3 |
Match the following
| (i) Photon | (a) Value is 4 for N shell |
| (ii) Electron | (b) Probability density |
| (iii) ψ2 | (c) Always positive value |
| (iv) Principal quantum number n | (d) Exhibits both momentum and wavelength |
Match species given in Column I with the electronic configuration given in Column II.
| Column I | Column II |
| (i) \[\ce{Cr}\] | (a) [Ar]3d84s0 |
| (ii) \[\ce{Fe^{2+}}\] | (b) [Ar]3d104s1 |
| (iii) \[\ce{Ni^{2+}}\] | (c) [Ar]3d64s0 |
| (iv) \[\ce{Cu}\] | (d) [Ar] 3d54s1 |
| (e) [Ar]3d64s2 |
In the case of R, S configuration the group having the highest priority is ______.
