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The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with

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प्रश्न

The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.

Based upon the above information, arrange the following orbitals in the increasing order of energy.

5f, 6d, 7s, 7p

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उत्तर

Orbitals s p d f
l 0 1 2 3

 

Orbitals n n + l
5f 5 8
6d 6 8
7s 7 7
7p 7 8

Thus the increasing order of energy is 7s < 5f < 6d < 7p.

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पाठ 2: Structure of Atom - Multiple Choice Questions (Type - I) [पृष्ठ १९]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 11
पाठ 2 Structure of Atom
Multiple Choice Questions (Type - I) | Q 27.(i).(d) | पृष्ठ १९

संबंधित प्रश्‍न

Choose the correct option.

“No two electrons in the same atoms can have identical set of four quantum numbers”. This statement is known as -


State Heisenberg uncertainty principle.


State and explain Pauli’s exclusion principle.


Write orbital notations for the electron in orbitals with the following quantum numbers.

n = 2, l = 1


Write electronic configurations of \[\ce{Fe, Fe2+, Fe3+}\].


Write condensed orbital notation of electronic configuration of the following element:

Chlorine (Z = 17)


If n = 3, what are the quantum number l and m?


Using the concept of quantum numbers, calculate the maximum numbers of electrons present in the ‘M’ shell. Give their distribution in shells, subshells, and orbitals.


Which of the following properties of atom could be explained correctly by Thomson Model of atom?


Total number of orbitals associated with third shell will be ______.


Out of the following pairs of electrons, identify the pairs of electrons present in degenerate orbitals:

(i)  (a) `n = 3, l = 2, m_l = -2, m_s = - 1/2`
  (b) `n = 3, l = 2, m_l = -1, m_s = - 1/2`
   
(ii)  (a) `n = 3, l = 1, m_l = 1, m_s = + 1/2`
  (b) `n = 3, l = 2, m_l = 1, m_s = + 1/2`
   
(iii) (a) `n = 4, l = 1, m_l = 1, m_s = + 1/2`
  (b) `n = 3, l = 2, m_l = 1, m_s = + 1/2`
   
(iv)  (a) `n = 3, l = 2, m_l = +2, m_s = - 1/2`
  (b) `n = 3, l = 2, m_l = +2, m_s = + 1/2`

Which of the following statements concerning the quantum numbers are correct?

(i) Angular quantum number determines the three dimensional shape of the orbital.

(ii) The principal quantum number determines the orientation and energy of the orbital.

(iii) Magnetic quantum number determines the size of the orbital.

(iv) Spin quantum number of an electron determines the orientation of the spin of electron relative to the chosen axis.


Nickel atom can lose two electrons to form \[\ce{Ni^{2+}}\] ion. The atomic number of nickel is 28. From which orbital will nickel lose two electrons.


The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.

Based upon the above information, solve the questions given below:

Which of the following orbitals has the lowest energy?

5p, 5d, 5f, 6s, 6p


What is the difference between the terms orbit and orbital?


Which of the following is the correct plot for the probability density ψ2 (r) as a function of distance 'r' of the electron from the nucleus for 2s orbitals?


Which of the following is not the permissible arrangement of electrons in an atom?


In assigning R - S configuration, which among the following groups has highest priority?


In the case of R, S configuration the group having the highest priority is ______.


What are the possible values of magnetic quantum number for p orbital?


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