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प्रश्न
The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.
Based upon the above information, arrange the following orbitals in the increasing order of energy.
5p, 4d, 5d, 4f, 6s
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उत्तर
| Orbitals | s | p | d | f |
| l | 0 | 1 | 2 | 3 |
| Orbitals | n | n + l |
| 5p | 5 | 6 |
| 4d | 4 | 6 |
| 5d | 5 | 7 |
| 4f | 4 | 7 |
| 6s | 6 | 6 |
Thus the increasing order of energy is 4d < 5p < 6s < 4f < 5d.
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संबंधित प्रश्न
Using s, p, d notations, describe the orbital with the following quantum numbers n = 4; l =3.
Choose the correct option.
p-orbitals are _________ in shape.
Give the names of quantum numbers.
Define the term Electronic configuration.
State and explain Pauli’s exclusion principle.
State Hund’s rule of maximum multiplicity with a suitable example.
Explain the anomalous behaviour of copper.
Explain the anomalous behaviour of chromium.
Write orbital notations for the electron in orbitals with the following quantum numbers.
n = 4, l = 2
Write condensed orbital notation of electronic configuration of the following element:
Oxygen (Z = 8)
How many electrons can fit in the orbital for which n = 4 and l = 2?
The probability density plots of 1s and 2s orbitals are given in Figure:
The density of dots in a region represents the probability density of finding electrons in the region.
On the basis of above diagram which of the following statements is incorrect?
Orbital angular momentum depends on ______.
Which of the following sets of quantum numbers are correct?
| `n` | `l` | `m_l` | |
| (i) | 1 | 1 | +2 |
| (ii) | 2 | 1 | +1 |
| (iii) | 3 | 2 | –2 |
| (iv) | 3 | 4 | –2 |
Which of the following statements concerning the quantum numbers are correct?
(i) Angular quantum number determines the three dimensional shape of the orbital.
(ii) The principal quantum number determines the orientation and energy of the orbital.
(iii) Magnetic quantum number determines the size of the orbital.
(iv) Spin quantum number of an electron determines the orientation of the spin of electron relative to the chosen axis.
Calculate the total number of angular nodes and radial nodes present in 3p orbital.
What is the difference between the terms orbit and orbital?
Match the quantum numbers with the information provided by these.
| Quantum number | Information provided |
| (i) Principal quantum number | (a) orientation of the orbital |
| (ii) Azimuthal quantum number | (b) energy and size of orbital |
| (iii) Magnetic quantum number | (c) spin of electron |
| (iv) Spin quantum number | (d) shape of the orbital |
