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The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with - Chemistry

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प्रश्न

The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.

Based upon the above information, arrange the following orbitals in the increasing order of energy.

4s, 3s, 3p, 4d

टीपा लिहा
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उत्तर

Orbitals s p d f
l 0 1 2 3

 

Orbitals n n + l
4s 4 4
3s 3 3
3p 3 4
4d 4 6

Thus the increasing order of energy is 3s < 3p < 4s < 4d.

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पाठ 2: Structure of Atom - Multiple Choice Questions (Type - I) [पृष्ठ १९]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 11
पाठ 2 Structure of Atom
Multiple Choice Questions (Type - I) | Q 27.(i).(b) | पृष्ठ १९

संबंधित प्रश्‍न

Using s, p, d notations, describe the orbital with the following quantum numbers n = 4; l = 2.


Choose the correct option.

p-orbitals are _________ in shape.


Choose the correct option.

“No two electrons in the same atoms can have identical set of four quantum numbers”. This statement is known as -


State and explain Pauli’s exclusion principle.


Explain the anomalous behaviour of chromium.


Write orbital notations for the electron in orbitals with the following quantum numbers.

n = 4, l = 2


Write orbital notations for the electron in orbitals with the following quantum numbers.

n = 3, l = 2


Write electronic configurations of \[\ce{Fe, Fe2+, Fe3+}\].


Write condensed orbital notation of electronic configuration of the following element:

Lithium (Z = 3)


Write condensed orbital notation of electronic configuration of the following element:

Oxygen (Z = 8)


Indicate the number of unpaired electrons in \[\ce{Si}\] (Z = 14).


The principal quantum number (n) and magnetic quantum number (ml) for the valence electrons of rubidium atom (Z = 37) are ____________ respectively.


Out of the following pairs of electrons, identify the pairs of electrons present in degenerate orbitals:

(i)  (a) `n = 3, l = 2, m_l = -2, m_s = - 1/2`
  (b) `n = 3, l = 2, m_l = -1, m_s = - 1/2`
   
(ii)  (a) `n = 3, l = 1, m_l = 1, m_s = + 1/2`
  (b) `n = 3, l = 2, m_l = 1, m_s = + 1/2`
   
(iii) (a) `n = 4, l = 1, m_l = 1, m_s = + 1/2`
  (b) `n = 3, l = 2, m_l = 1, m_s = + 1/2`
   
(iv)  (a) `n = 3, l = 2, m_l = +2, m_s = - 1/2`
  (b) `n = 3, l = 2, m_l = +2, m_s = + 1/2`

Which of the following orbitals are degenerate?

3dxy, 4dxy 3dz2, 3dyz, 4dyz, 4dz2  


Calculate the total number of angular nodes and radial nodes present in 3p orbital.


The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.

Based upon the above information, solve the questions given below:

Which of the following orbitals has the lowest energy?

4d, 4f, 5s, 5p


The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.

Based upon the above information, solve the questions given below:

Which of the following orbitals has the lowest energy?

5p, 5d, 5f, 6s, 6p


Match the quantum numbers with the information provided by these.

Quantum number Information provided
(i) Principal quantum number (a) orientation of the orbital
(ii) Azimuthal quantum number (b) energy and size of orbital
(iii) Magnetic quantum number (c) spin of electron
(iv) Spin quantum number (d) shape of the orbital

Match the following

(i) Photon (a) Value is 4 for N shell
(ii) Electron (b) Probability density
(iii) ψ2 (c) Always positive value
(iv) Principal quantum number n (d) Exhibits both momentum and wavelength

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