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Out of the following pairs of electrons, identify the pairs of electrons present in degenerate orbitals: (i) (a) n=3,l=2,ml=-2,ms=-12 (b) n=3,l=2,ml=-1,ms=-12 (ii) (a) n=3,l=1,ml=1,ms=+12 (b) n=3

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प्रश्न

Out of the following pairs of electrons, identify the pairs of electrons present in degenerate orbitals:

(i)  (a) `n = 3, l = 2, m_l = -2, m_s = - 1/2`
  (b) `n = 3, l = 2, m_l = -1, m_s = - 1/2`
   
(ii)  (a) `n = 3, l = 1, m_l = 1, m_s = + 1/2`
  (b) `n = 3, l = 2, m_l = 1, m_s = + 1/2`
   
(iii) (a) `n = 4, l = 1, m_l = 1, m_s = + 1/2`
  (b) `n = 3, l = 2, m_l = 1, m_s = + 1/2`
   
(iv)  (a) `n = 3, l = 2, m_l = +2, m_s = - 1/2`
  (b) `n = 3, l = 2, m_l = +2, m_s = + 1/2`
टीपा लिहा
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उत्तर

(i)  (a) `n = 3, l = 2, m_l = -2, m_s = - 1/2`
  (b) `n = 3, l = 2, m_l = -1, m_s = - 1/2`
   
(iv)  (a) `n = 3, l = 2, m_l = +2, m_s = - 1/2`
  (b) `n = 3, l = 2, m_l = +2, m_s = + 1/2`

Explanation:

In a multi-electron atomic system the energy of an electron depends not only on its principal quantum number (shell), but also on its azimuthal quantum number (subshell). Electrons having the same shells and same subshells have the same energy and they are known as degenerate orbitals.

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पाठ 2: Structure of Atom - Multiple Choice Questions (Type - I) [पृष्ठ १७]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 11
पाठ 2 Structure of Atom
Multiple Choice Questions (Type - I) | Q 18 | पृष्ठ १७

संबंधित प्रश्‍न

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Give the names of quantum numbers.


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Write orbital notations for the electron in orbitals with the following quantum numbers.

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Write condensed orbital notation of electronic configuration of the following element:

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Write condensed orbital notation of electronic configuration of the following element:

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Draw shapes of 2p orbitals.


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Using the concept of quantum numbers, calculate the maximum numbers of electrons present in the ‘M’ shell. Give their distribution in shells, subshells, and orbitals.


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The three electrons have the following set of quantum numbers:

X = 6, 1, −1, `+1/2`

Y = 6, 0, 0, `+1/2`

Z = 5, 1, 0, `+1/2`

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The pair of ions having same electronic configuration is ______.


The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.

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4s, 3s, 3p, 4d


Match the quantum numbers with the information provided by these.

Quantum number Information provided
(i) Principal quantum number (a) orientation of the orbital
(ii) Azimuthal quantum number (b) energy and size of orbital
(iii) Magnetic quantum number (c) spin of electron
(iv) Spin quantum number (d) shape of the orbital

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