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प्रश्न
Indicate the number of unpaired electrons in \[\ce{Si}\] (Z = 14).
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उत्तर
Electronic configuration of \[\ce{Si}\] (Z = 14) is 1s2 2s2 2p6 3s2 3p2
Orbital diagram:
| ↑↓ | ↑↓ | ↑↓ | ↑↓ | ↑↓ | ↑↓ | ↑ | ↑ | |
| 1s | 2s | 2p | 3s | 3p | ||||
Number of unpaired electrons = 2
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संबंधित प्रश्न
Using s, p, d notations, describe the orbital with the following quantum numbers n = 1, l = 0.
Using s, p, d notations, describe the orbital with the following quantum numbers n = 4; l = 2.
Choose the correct option.
“No two electrons in the same atoms can have identical set of four quantum numbers”. This statement is known as -
Give the names of quantum numbers.
State Hund’s rule of maximum multiplicity with a suitable example.
Explain the anomalous behaviour of copper.
Explain the anomalous behaviour of chromium.
Write condensed orbital notation of electronic configuration of the following element:
Oxygen (Z = 8)
Write condensed orbital notation of electronic configuration of the following element:
Calcium (Z = 20)
Draw shapes of 2s orbitals.
Explain in brief, the significance of the azimuthal quantum number.
Using the concept of quantum numbers, calculate the maximum numbers of electrons present in the ‘M’ shell. Give their distribution in shells, subshells, and orbitals.
The principal quantum number (n) and magnetic quantum number (ml) for the valence electrons of rubidium atom (Z = 37) are ____________ respectively.
Which one of the following orders is CORRECT in case of energy of the given subshells?
P: n = 4; l = 3
Q: n = 5; I = 1
R: n = 5; l = 0
S: n = 4; l = 2
How many electrons can fit in the orbital for which n = 4 and l = 2?
Which of the following options does not represent ground state electronic configuration of an atom?
Number of angular nodes for 4d orbital is ______.
Out of the following pairs of electrons, identify the pairs of electrons present in degenerate orbitals:
| (i) | (a) `n = 3, l = 2, m_l = -2, m_s = - 1/2` |
| (b) `n = 3, l = 2, m_l = -1, m_s = - 1/2` | |
| (ii) | (a) `n = 3, l = 1, m_l = 1, m_s = + 1/2` |
| (b) `n = 3, l = 2, m_l = 1, m_s = + 1/2` | |
| (iii) | (a) `n = 4, l = 1, m_l = 1, m_s = + 1/2` |
| (b) `n = 3, l = 2, m_l = 1, m_s = + 1/2` | |
| (iv) | (a) `n = 3, l = 2, m_l = +2, m_s = - 1/2` |
| (b) `n = 3, l = 2, m_l = +2, m_s = + 1/2` |
Which of the following sets of quantum numbers are correct?
| `n` | `l` | `m_l` | |
| (i) | 1 | 1 | +2 |
| (ii) | 2 | 1 | +1 |
| (iii) | 3 | 2 | –2 |
| (iv) | 3 | 4 | –2 |
Nickel atom can lose two electrons to form \[\ce{Ni^{2+}}\] ion. The atomic number of nickel is 28. From which orbital will nickel lose two electrons.
Which of the following orbitals are degenerate?
3dxy, 4dxy 3dz2, 3dyz, 4dyz, 4dz2
The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.
Based upon the above information, arrange the following orbitals in the increasing order of energy.
5p, 4d, 5d, 4f, 6s
The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.
Based upon the above information, solve the questions given below:
Which of the following orbitals has the lowest energy?
4d, 4f, 5s, 5p
Match the following
| (i) Photon | (a) Value is 4 for N shell |
| (ii) Electron | (b) Probability density |
| (iii) ψ2 | (c) Always positive value |
| (iv) Principal quantum number n | (d) Exhibits both momentum and wavelength |
Which of the following is the correct plot for the probability density ψ2 (r) as a function of distance 'r' of the electron from the nucleus for 2s orbitals?
In assigning R - S configuration, which among the following groups has highest priority?
In the case of R, S configuration the group having the highest priority is ______.
