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Explain in brief, the significance of the azimuthal quantum number. - Chemistry

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प्रश्न

Explain in brief, the significance of the azimuthal quantum number.

थोडक्यात उत्तर
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उत्तर

  1. Azimuthal quantum number is also known as the subsidiary quantum number and is represented by the letter l.
  2. It represents the subshell to which the electron belongs. It also defines the shape of the orbital that is occupied by the electron.
  3. Its value depends upon the value of principal quantum number ‘n’. It can have only positive values between 0 and (n − 1).
  4. Atomic orbitals with the same value of ‘n’ but different values of ‘l’ constitute a subshell belonging to the shell for the given ‘n’. The azimuthal quantum number gives the number of subshells in a principal shell. The subshells have l to be 0, 1, 2, 3 … which are represented by symbols s, p, d, f, … respectively.
    Principal shell Value of n Permissible value of l Possible subshell Number of subshells in shell
    K 1 0 s 1
    L 2 0, 1 s, p 2
    M 3 0, 1, 2 s, p, d 3
    N 4 0, 1, 2, 3 s, p, d, f 4
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पाठ 4: Structure of Atom - Exercises [पृष्ठ ५४]

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बालभारती Chemistry [English] Standard 11 Maharashtra State Board
पाठ 4 Structure of Atom
Exercises | Q 6. (N) | पृष्ठ ५४

संबंधित प्रश्‍न

Using s, p, d notations, describe the orbital with the following quantum numbers n = 4; l = 2.


State Hund’s rule of maximum multiplicity with a suitable example.


Explain the anomalous behaviour of copper.


Explain the anomalous behaviour of chromium.


Write orbital notations for the electron in orbitals with the following quantum numbers.

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Write orbital notations for the electron in orbitals with the following quantum numbers.

n = 4, l = 2


Write electronic configurations of \[\ce{Fe, Fe2+, Fe3+}\].


Write condensed orbital notation of electronic configuration of the following element:

Lithium (Z = 3)


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Indicate the number of unpaired electrons in \[\ce{Si}\] (Z = 14).


Which mineral among the following contains vanadium in it?


Which one of the following orders is CORRECT in case of energy of the given subshells?

P: n = 4; l = 3

Q: n = 5; I = 1

R: n = 5; l = 0

S: n = 4; l = 2


The probability density plots of 1s and 2s orbitals are given in Figure:


The density of dots in a region represents the probability density of finding electrons in the region.

On the basis of above diagram which of the following statements is incorrect?


The number of radial nodes for 3p orbital is ______.


Total number of orbitals associated with third shell will be ______.


Orbital angular momentum depends on ______.


Which of the following statements concerning the quantum numbers are correct?

(i) Angular quantum number determines the three dimensional shape of the orbital.

(ii) The principal quantum number determines the orientation and energy of the orbital.

(iii) Magnetic quantum number determines the size of the orbital.

(iv) Spin quantum number of an electron determines the orientation of the spin of electron relative to the chosen axis.


Which of the following orbitals are degenerate?

3dxy, 4dxy 3dz2, 3dyz, 4dyz, 4dz2  


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Based upon the above information, arrange the following orbitals in the increasing order of energy.

1s, 2s, 3s, 2p


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Based upon the above information, arrange the following orbitals in the increasing order of energy.

4s, 3s, 3p, 4d


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Based upon the above information, solve the questions given below:

Which of the following orbitals has the lowest energy?

4d, 4f, 5s, 5p


The electronic configuration of valence shell of Cu is 3d104s1 and not 3d94s2. How is this configuration explained?


Match species given in Column I with the electronic configuration given in Column II.

Column I Column II
(i) \[\ce{Cr}\] (a) [Ar]3d84s0
(ii) \[\ce{Fe^{2+}}\] (b) [Ar]3d104s1
(iii) \[\ce{Ni^{2+}}\] (c) [Ar]3d64s0
(iv) \[\ce{Cu}\] (d) [Ar] 3d54s1
  (e) [Ar]3d64s2

Which of the following element do not follow Aufbau principle?


Which one of the following laws will represent the pairing of electrons in a subshell after each orbital is filled with one electron?


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