हिंदी

Explain in brief, the significance of the azimuthal quantum number.

Advertisements
Advertisements

प्रश्न

Explain in brief, the significance of the azimuthal quantum number.

संक्षेप में उत्तर
Advertisements

उत्तर

  1. Azimuthal quantum number is also known as the subsidiary quantum number and is represented by the letter l.
  2. It represents the subshell to which the electron belongs. It also defines the shape of the orbital that is occupied by the electron.
  3. Its value depends upon the value of principal quantum number ‘n’. It can have only positive values between 0 and (n − 1).
  4. Atomic orbitals with the same value of ‘n’ but different values of ‘l’ constitute a subshell belonging to the shell for the given ‘n’. The azimuthal quantum number gives the number of subshells in a principal shell. The subshells have l to be 0, 1, 2, 3 … which are represented by symbols s, p, d, f, … respectively.
    Principal shell Value of n Permissible value of l Possible subshell Number of subshells in shell
    K 1 0 s 1
    L 2 0, 1 s, p 2
    M 3 0, 1, 2 s, p, d 3
    N 4 0, 1, 2, 3 s, p, d, f 4
shaalaa.com
  क्या इस प्रश्न या उत्तर में कोई त्रुटि है?
अध्याय 4: Structure of Atom - Exercises [पृष्ठ ५४]

APPEARS IN

बालभारती Chemistry [English] Standard 11 Maharashtra State Board
अध्याय 4 Structure of Atom
Exercises | Q 6. (N) | पृष्ठ ५४

संबंधित प्रश्न

Using s, p, d notations, describe the orbital with the following quantum numbers n = 1, l = 0.


Using s, p, d notations, describe the orbital with the following quantum numbers n = 3; l =1.


State and explain Pauli’s exclusion principle.


Explain the anomalous behaviour of copper.


Write orbital notations for the electron in orbitals with the following quantum numbers.

n = 2, l = 1


Write electronic configurations of \[\ce{Fe, Fe2+, Fe3+}\].


Write condensed orbital notation of electronic configuration of the following element:

Oxygen (Z = 8)


Write condensed orbital notation of electronic configuration of the following element:

Calcium (Z = 20)


Draw shapes of 2s orbitals.


Using the concept of quantum numbers, calculate the maximum numbers of electrons present in the ‘M’ shell. Give their distribution in shells, subshells, and orbitals.


The designation of a subshell with n = 6 and l = 2 is ____________.


Which one of the following orders is CORRECT in case of energy of the given subshells?

P: n = 4; l = 3

Q: n = 5; I = 1

R: n = 5; l = 0

S: n = 4; l = 2


How many electrons in 19K have n = 3, l = 1?


Which one of the following is NOT possible?


Which of the following options does not represent ground state electronic configuration of an atom?


Number of angular nodes for 4d orbital is ______.


Total number of orbitals associated with third shell will be ______.


Out of the following pairs of electrons, identify the pairs of electrons present in degenerate orbitals:

(i)  (a) `n = 3, l = 2, m_l = -2, m_s = - 1/2`
  (b) `n = 3, l = 2, m_l = -1, m_s = - 1/2`
   
(ii)  (a) `n = 3, l = 1, m_l = 1, m_s = + 1/2`
  (b) `n = 3, l = 2, m_l = 1, m_s = + 1/2`
   
(iii) (a) `n = 4, l = 1, m_l = 1, m_s = + 1/2`
  (b) `n = 3, l = 2, m_l = 1, m_s = + 1/2`
   
(iv)  (a) `n = 3, l = 2, m_l = +2, m_s = - 1/2`
  (b) `n = 3, l = 2, m_l = +2, m_s = + 1/2`

Nickel atom can lose two electrons to form \[\ce{Ni^{2+}}\] ion. The atomic number of nickel is 28. From which orbital will nickel lose two electrons.


Which of the following orbitals are degenerate?

3dxy, 4dxy 3dz2, 3dyz, 4dyz, 4dz2  


Calculate the total number of angular nodes and radial nodes present in 3p orbital.


The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.

Based upon the above information, solve the questions given below:

Which of the following orbitals has the lowest energy?

5p, 5d, 5f, 6s, 6p


The electronic configuration of valence shell of Cu is 3d104s1 and not 3d94s2. How is this configuration explained?


Match the following

(i) Photon (a) Value is 4 for N shell
(ii) Electron (b) Probability density
(iii) ψ2 (c) Always positive value
(iv) Principal quantum number n (d) Exhibits both momentum and wavelength

Which of the following is the correct plot for the probability density ψ2 (r) as a function of distance 'r' of the electron from the nucleus for 2s orbitals?


In assigning R - S configuration, which among the following groups has highest priority?


Which of the following element do not follow Aufbau principle?


What are the possible values of magnetic quantum number for p orbital?


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×