हिंदी

Explain in brief, the significance of the azimuthal quantum number. - Chemistry

Advertisements
Advertisements

प्रश्न

Explain in brief, the significance of the azimuthal quantum number.

संक्षेप में उत्तर
Advertisements

उत्तर

  1. Azimuthal quantum number is also known as the subsidiary quantum number and is represented by the letter l.
  2. It represents the subshell to which the electron belongs. It also defines the shape of the orbital that is occupied by the electron.
  3. Its value depends upon the value of principal quantum number ‘n’. It can have only positive values between 0 and (n − 1).
  4. Atomic orbitals with the same value of ‘n’ but different values of ‘l’ constitute a subshell belonging to the shell for the given ‘n’. The azimuthal quantum number gives the number of subshells in a principal shell. The subshells have l to be 0, 1, 2, 3 … which are represented by symbols s, p, d, f, … respectively.
    Principal shell Value of n Permissible value of l Possible subshell Number of subshells in shell
    K 1 0 s 1
    L 2 0, 1 s, p 2
    M 3 0, 1, 2 s, p, d 3
    N 4 0, 1, 2, 3 s, p, d, f 4
shaalaa.com
  क्या इस प्रश्न या उत्तर में कोई त्रुटि है?
अध्याय 4: Structure of Atom - Exercises [पृष्ठ ५४]

APPEARS IN

बालभारती Chemistry [English] Standard 11 Maharashtra State Board
अध्याय 4 Structure of Atom
Exercises | Q 6. (N) | पृष्ठ ५४

संबंधित प्रश्न

Using s, p, d notations, describe the orbital with the following quantum numbers n = 4; l =3.


Choose the correct option.

p-orbitals are _________ in shape.


Choose the correct option.

Principal Quantum number describes -


State and explain Pauli’s exclusion principle.


Explain the anomalous behaviour of copper.


Explain the anomalous behaviour of chromium.


Write orbital notations for the electron in orbitals with the following quantum numbers.

n = 2, l = 1


Write orbital notations for the electron in orbitals with the following quantum numbers.

n = 3, l = 2


Write electronic configurations of \[\ce{Fe, Fe2+, Fe3+}\].


Write condensed orbital notation of electronic configuration of the following element:

Chlorine (Z = 17)


Write condensed orbital notation of electronic configuration of the following element:

Calcium (Z = 20)


If n = 3, what are the quantum number l and m?


The electronic configuration of oxygen is written as 1s2 2s2 \[\ce{2p^2_{{x}}}\] \[\ce{2p^1_{{y}}}\] \[\ce{2p^1_{{z}}}\] and not as 1s2 2s2 \[\ce{2p^2_{{x}}}\], \[\ce{2p^2_{{y}}}\] \[\ce{2p^0_{{z}}}\], Explain.


Using the concept of quantum numbers, calculate the maximum numbers of electrons present in the ‘M’ shell. Give their distribution in shells, subshells, and orbitals.


Which of the following options does not represent ground state electronic configuration of an atom?


Which of the following properties of atom could be explained correctly by Thomson Model of atom?


The number of radial nodes for 3p orbital is ______.


The pair of ions having same electronic configuration is ______.


In which of the following pairs, the ions are iso-electronic?

(i) \[\ce{Na^{+}, Mg^{2+}}\]

(ii) \[\ce{Al3^{+}, O-}\]

(iii) \[\ce{Na+ , O2-}\]

(iv) \[\ce{N3-, Cl-}\]


Which of the following statements concerning the quantum numbers are correct?

(i) Angular quantum number determines the three dimensional shape of the orbital.

(ii) The principal quantum number determines the orientation and energy of the orbital.

(iii) Magnetic quantum number determines the size of the orbital.

(iv) Spin quantum number of an electron determines the orientation of the spin of electron relative to the chosen axis.


Nickel atom can lose two electrons to form \[\ce{Ni^{2+}}\] ion. The atomic number of nickel is 28. From which orbital will nickel lose two electrons.


Which of the following orbitals are degenerate?

3dxy, 4dxy 3dz2, 3dyz, 4dyz, 4dz2  


The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.

Based upon the above information, arrange the following orbitals in the increasing order of energy.

1s, 2s, 3s, 2p


The electronic configuration of valence shell of Cu is 3d104s1 and not 3d94s2. How is this configuration explained?


What is the difference between the terms orbit and orbital?


In assigning R - S configuration, which among the following groups has highest priority?


Which one of the following laws will represent the pairing of electrons in a subshell after each orbital is filled with one electron?


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×